2,7-二氨基-9,9-二辛基-9H-芴合成路线 （共 4 条）
反应条件
hydrogenchloride; water in tetrahydrofuran
T=23°C; 8 h; Inert atmosphere;
参考文献
Rostami, Ali; Guerin, Gerald; Taylor, Mark S.
Macromolecules, 2013 , vol. 46, # 16 p. 6439 - 6450
反应条件
1: tris-(dibenzylideneacetone)dipalladium(0); 2,2'-bis-(diphenylphosphino)-1,1'- binaphthyl; sodium t-butanolate / toluene / 12 h / 80 °C / Inert atmosphere
2: hydrogenchloride; water / tetrahydrofuran / 8 h / 23 °C / Inert atmosphere
View Scheme
参考文献
Rostami, Ali; Wei, Chu Jun; Guerin, Gerald; Taylor, Mark S.
Angewandte Chemie - International Edition, 2011 , vol. 50, # 9 p. 2059 - 2062
反应条件
1: tetrabutylammomium bromide; sodium hydroxide / dimethyl sulfoxide; water / 12 h / 100 °C
2: tris-(dibenzylideneacetone)dipalladium(0); 2,2'-bis-(diphenylphosphino)-1,1'- binaphthyl; sodium t-butanolate / toluene / 12 h / 80 °C
3: hydrogenchloride / tetrahydrofuran / 12 h / 23 °C
View Scheme
参考文献
Rostami, Ali; Guerin, Gerald; Taylor, Mark S.
Macromolecules, 2013 , vol. 46, # 16 p. 6439 - 6450
反应条件
1: tetrabutylammomium bromide; sodium hydroxide / dimethyl sulfoxide; water / 12 h / 100 °C
2: tris-(dibenzylideneacetone)dipalladium(0); 2,2'-bis-(diphenylphosphino)-1,1'- binaphthyl; sodium t-butanolate / toluene / 12 h / 80 °C
3: hydrogenchloride / tetrahydrofuran / 12 h / 23 °C
View Scheme
参考文献
Rostami, Ali; Guerin, Gerald; Taylor, Mark S.
Macromolecules, 2013 , vol. 46, # 16 p. 6439 - 6450
