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结构式
乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
853955-69-8
合成路线
（共 89 条）
853955-69-8
+
696-62-8
4-碘苯甲醚
→
反应条件
613-37-6
4-甲氧基联苯
反应条件
dpca; potassium carbonate; palladium dichloride in water; dimethyl sulfoxide T=50°C; 16 h;
参考文献
Nakao, Yoshiaki; Hiyama, Tamejiro
Patent: US2009/69577 A1, 2009 ;
Location in patent: Page/Page column 20 ;
853955-69-8
+
104-92-7
4-溴苯甲醚
→
反应条件
613-37-6
4-甲氧基联苯
+
321903-29-1
1,3-二氢-1,1-二甲基-2,1-苯并氧硅杂环戊二烯
反应条件
potassium carbonate; copper(l) iodide; bis(η3-allyl-μ-chloropalladium(II)); dicyclohexyl(2',6'-diisopropoxy-[1,1'-biphenyl]-2-yl)phosphine in tetrahydrofuran; N,N-dimethyl-formamide T=75°C; 23 h; Product distribution / selectivity;
参考文献
US2009/69577 A1, ;
Page/Page column 21-22; 24 ;
853955-69-8
+
623-12-1
4-氯苯甲醚
→
反应条件
613-37-6
4-甲氧基联苯
+
321903-29-1
1,3-二氢-1,1-二甲基-2,1-苯并氧硅杂环戊二烯
反应条件
1,1'-bis-(diphenylphosphino)ferrocene; [NiCl2(1,2-dimethoxyethane)]; caesium carbonate; zinc; tri-cyclo-hexyl-phosphine in ethylene glycol dimethyl ether; N,N-dimethyl-formamide T=20 - 80°C; Suzuki-Miyaura cross-coupling reaction; 30 h; Inert atmosphere; chemoselective reaction;
参考文献
Tang, Shi; Takeda, Masahide; Nakao, Yoshiaki; Hiyama, Tamejiro
Chemical Communications, 2011 , vol. 47, # 1 p. 307 - 309
853955-69-8
+
5029-67-4
2-碘吡啶
→
反应条件
1008-89-5
2-苯基吡啶
反应条件
dpca; potassium carbonate; palladium dichloride in water; dimethyl sulfoxide T=50°C; 13 h;
参考文献
Nakao, Yoshiaki; Imanaka, Hidekazu; Sahoo, Akhila K.; Yada, Akira; Hiyama, Tamejiro
Journal of the American Chemical Society, 2005 , vol. 127, # 19 p. 6952 - 6953
853955-69-8
+
109-04-6
邻溴吡啶
→
反应条件
1008-89-5
2-苯基吡啶
+
321903-29-1
1,3-二氢-1,1-二甲基-2,1-苯并氧硅杂环戊二烯
反应条件
copper(l) iodide; bis(η3-allyl-μ-chloropalladium(II)); potassium carbonate; dicyclohexyl(2',6'-diisopropoxy-[1,1'-biphenyl]-2-yl)phosphine in tetrahydrofuran; N,N-dimethyl-formamide T=75°C; 22 h; Inert atmosphere;
参考文献
Bulletin of the Chemical Society of Japan, , vol. 83, # 5 p. 554 - 569
853955-69-8
+
623-43-8
巴豆酸甲酯
→
反应条件
3461-39-0
3-苯基丁酸甲酯
反应条件
[Rh(OH)(cycloocta-1,5-diene)]2 in tetrahydrofuran T=35°C; 4 h;
参考文献
Nakao, Yoshiaki; Chen, Jinshui; Imanaka, Hidekazu; Hiyama, Tamejiro; Ichikawa, Yoshitaka; Duan, Wei-Liang; Shintani, Ryo; Hayashi, Tamio
Journal of the American Chemical Society, 2007 , vol. 129, # 29 p. 9137 - 9143
853955-69-8
+
623-91-6
富马酸二乙酯
→
反应条件
34861-81-9
二乙基2-苯基丁二酸酯
反应条件
[Rh(OH)(cycloocta-1,5-diene)]2 in tetrahydrofuran T=35°C; 8 h;
参考文献
Nakao, Yoshiaki; Chen, Jinshui; Imanaka, Hidekazu; Hiyama, Tamejiro; Ichikawa, Yoshitaka; Duan, Wei-Liang; Shintani, Ryo; Hayashi, Tamio
Journal of the American Chemical Society, 2007 , vol. 129, # 29 p. 9137 - 9143
853955-69-8
+
68716-49-4
4-溴苯硼酸频那醇酯
→
反应条件
144432-80-4
4-双苯硼酸频那醇酯
反应条件
1: [2-(hydroxymethyl)phenyl]dimethyl(phenyl)silane With n-butyllithium in tetrahydrofuran T=-78 - 20°C; 2: 4-bromophenylboronic acid pinacol ester With copper(l) iodide; bis(η3-allyl-μ-chloropalladium(II)); dicyclohexyl(2',6'-diisopropoxy-[1,1'-biphenyl]-2-yl)phosphine in tetrahydrofuran; N,N-dimethyl-formamide T=75°C; 11 h;
参考文献
US2009/69577 A1, ;
Page/Page column 24 ;
853955-69-8
+
68716-49-4
4-溴苯硼酸频那醇酯
→
反应条件
144432-80-4
4-双苯硼酸频那醇酯
+
321903-29-1
1,3-二氢-1,1-二甲基-2,1-苯并氧硅杂环戊二烯
反应条件
1: [2-(hydroxymethyl)phenyl]dimethyl(phenyl)silane With n-butyllithium in tetrahydrofuran; hexane T=0°C; 0.0833333 h; Inert atmosphere; 2: 4-bromophenylboronic acid pinacol ester With copper(l) iodide; bis(η3-allyl-μ-chloropalladium(II)); dicyclohexyl(2',6'-diisopropoxy-[1,1'-biphenyl]-2-yl)phosphine in tetrahydrofuran; hexane; N,N-dimethyl-formamide T=75°C; 11 h; Inert atmosphere;
参考文献
Bulletin of the Chemical Society of Japan, , vol. 83, # 5 p. 554 - 569
853955-69-8
+
117635-21-9
2,5-双(己基)-1,4-二溴苯
→
反应条件
178426-66-9
反应条件
1,1'-bis-(diphenylphosphino)ferrocene; copper(I) bromide dimethylsulfide complex; Pd[P(o-tol)3]2; caesium carbonate in tetrahydrofuran; 1-methyl-pyrrolidin-2-one T=50°C; 5 h; Inert atmosphereMolecular sieve;
参考文献
Shimizu, Kenta; Minami, Yasunori; Nakao, Yoshiaki; Ohya, Ken-Ichiro; Ikehira, Hideyuki; Hiyama, Tamejiro
Chemistry Letters, 2013 , vol. 42, # 1 p. 45 - 47
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