2’-甲基-4-甲氧基二苯胺合成路线 （共 8 条）
反应条件
tris(dibenzylideneacetone)dipalladium (0); sodium t-butanolate; N-[2'-(dicyclohexylphosphino)-1,1'-biphenyl-2-yl]-N,N-dimethylamine in 1,4-dioxane
T=45°C;
参考文献
Ali; Buchwald
Journal of Organic Chemistry, 2001 , vol. 66, # 8 p. 2560 - 2565
反应条件
sodium t-butanolate; tris(dibenzylideneacetone)dipalladium (0); P(i-BuNCH2CH2)3N in toluene
T=100°C; Buchwald-Hartwig amination; 24 h;
参考文献
Shen, Huafeng; Zhang, Zhong-Ping; Li, Jing-Hua
Journal of Chemical Research, 2010 , # 3 p. 163 - 166
反应条件
(2-phenyl-1H-inden-3-yl)-dicyclohexylphosphinium tetrafluoroborate; bis(dibenzylideneacetone)-palladium(0); sodium t-butanolate in ethylene glycol dimethyl ether
T=20 - 120°C; Buchwald-Hartwig amination; Inert atmosphere;
参考文献
Chen, Lei; Yu, Guang-Ao; Li, Fang; Zhu, Xiaolei; Zhang, Bei; Guo, Rui; Li, Xiaozhi; Yang, Qihua; Jin, Shan; Liu, Chenchen; Liu, Sheng-Hua
Journal of Organometallic Chemistry, 2010 , vol. 695, # 14 p. 1768 - 1775
反应条件
C22H26Cl2NPPd; sodium t-butanolate in toluene
T=110°C; 22 h; Inert atmosphere;
参考文献
Samblanet, Danielle C.; Schmidt, Joseph A. R.
Journal of Organometallic Chemistry, 2012 , vol. 720, p. 7 - 18,12
反应条件
1,1'-bis-(diphenylphosphino)ferrocene; [Ni0(1,5-cyclooctadiene)2]; sodium t-butanolate in toluene
T=20 - 105°C; Inert atmosphere;
参考文献
Ackermann, Lutz; Sandmann, Rene; Song, Weifeng
Organic Letters, 2011 , vol. 13, # 7 p. 1784 - 1786
反应条件
1: 2-nitrosotoluene With copper(l) chloride in N,N-dimethyl-formamide
T=55°C; 0.666667 h;
2: (4-methoxyphenyl)-boronic acid in N,N-dimethyl-formamide
T=55°C; 16 h;
参考文献
Yu, Ying; Srogl, Jiri; Liebeskind, Lanny S
Organic letters, 2004 , vol. 6, # 15 p. 2631 - 2634
反应条件
potassium tert-butylate; copper(l) iodide in toluene
T=135°C; 14 h;
参考文献
Kelkar, Ashutosh A.; Patil, Nandkumar M.; Chaudhari, Raghunath V.
Tetrahedron Letters, 2002 , vol. 43, # 40 p. 7143 - 7146
参考文献
Sunagawa; Ichii
Yakugaku Zasshi, 1959 , vol. 79, p. 1409
Chem.Abstr., 1960 , p. 6729
