叔丁基(5-己烯基氧基)二甲基硅烷合成路线 （共 17 条）
反应条件
1: 86 percent / Et3N; DMAP / CH2Cl2 / 1.5 h / 20 °C
2: Cp2ZrH(Cl) / toluene / 12 h / 20 °C
View Scheme
参考文献
Evans, David A.; Barnes, David M.; Johnson, Jeffrey S.; Lectka, Thomas; Von Matt, Peter; Miller, Scott J.; Murry, Jerry A.; Norcross, Roger D.; Shaughnessy, Eileen A.; Campos, Kevin R.
Journal of the American Chemical Society, 1999 , vol. 121, # 33 p. 7582 - 7594
反应条件
1: 86 percent / Et3N; DMAP / CH2Cl2 / 1.5 h / 20 °C
2: Cp2ZrH(Cl) / toluene / 12 h / 20 °C
View Scheme
参考文献
Evans, David A.; Barnes, David M.; Johnson, Jeffrey S.; Lectka, Thomas; Von Matt, Peter; Miller, Scott J.; Murry, Jerry A.; Norcross, Roger D.; Shaughnessy, Eileen A.; Campos, Kevin R.
Journal of the American Chemical Society, 1999 , vol. 121, # 33 p. 7582 - 7594
反应条件
n-butyllithium
-78 deg C to r.t.;
参考文献
Bergmeier, Stephen C.; Seth, Punit P.
Tetrahedron Letters, 1995 , vol. 36, # 22 p. 3793 - 3796
反应条件
1: With Dess-Martin periodane in dichloromethane
T=20°C; 0.833333 h;
2: With triethylamine in methanol
T=20°C;
参考文献
Andreou, Thanos; Bures, Jordi; Vilarrasa, Jaume
Tetrahedron Letters, 2010 , vol. 51, # 14 p. 1863 - 1866
反应条件
FeCl2(TMS-SciOPP)
T=80°C; 12 h;
参考文献
Kawamura, Shintaro; Kawabata, Tatsuya; Ishizuka, Kentaro; Nakamura, Masaharu
Chemical Communications, 2012 , vol. 48, # 75 p. 9376 - 9378
反应条件
oxygen; 1-n-butyl-3-methylimidazolium tetrafluoroborate; copper(l) chloride; palladium dichloride in water
T=60°C; Wacker oxidation; 58 h;
参考文献
Ansari; Joyasawal, Sipak; Gupta, Manoj K.; Yadav; Gree
Tetrahedron Letters, 2005 , vol. 46, # 44 p. 7507 - 7510
反应条件
1: With ozone in dichloromethane
2: With dimethylsulfide; triethylamine in dichloromethane
参考文献
Krafft, Marie E.; Bonaga, Llorente V. R.; Felts, Andrew S.; Hirosawa, Chitaru; Kerrigan, Sean
Journal of Organic Chemistry, 2003 , vol. 68, # 15 p. 6039 - 6042
