4,4,5,5-四甲基-2-(3,3,5,5-四甲基-1-环己烯-1-基)-1,3,2-二噁硼烷合成路线 (共 2 条)
反应条件
potassium acetate; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II) dichloromethane adduct in 1,4-dioxane T=80°C; 16.5 h;
参考文献
US2005/261291 A1, ;
Page/Page column 61 ;
反应条件
1: 3.3.5.5-Tetramethylcyclohexanon-p-tosylhydrazon With n-butyllithium; N,N,N',N,-tetramethylethylenediamine in hexane T=-78 - 20°C; Shapiro reaction; Inert atmosphere; 2: 2-isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane in hexane T=-78 - 20°C; 4 h; Inert atmosphere;
参考文献
Rauniyar, Vivek; Zhai, Huimin; Hall, Dennis G.
Synthetic Communications, 2008 , vol. 38, # 22 p. 3984 - 3995