反应条件
in N,N-dimethyl-formamide Electrochem. Process; electrochemical generation of O2(1-) from O2 supplied to the cathode compartment (H-cell, DMF, supporting electrolyte (C4H9)4NPF6); pouring catholyte (with excess O2(1-)) into a flask containing flourene; bubbling O2, 10min, dark;; diln. of catholyte with H2O; extn. with diethyl ether; drying; removal of solvent, vac.; column chromy. (silica gel; eluent: hexane/CH2Cl2 (50percent));;
参考文献
Journal of Organometallic Chemistry, , vol. 273, # 3 p. 319 - 322
