sulfuric acid

in dichloromethane; pentane under N2, 1-hexene treated with BHBr2*SMe2 in CH2Cl2 followed by treating with isopropyl alcohol in pentane at 0°C; distd., elem. anal.;

1: hexane; diethyl ether 2: di-tert-butyl peroxide / further solvent(s) View Scheme

1: hexane; diethyl ether 2: di-tert-butyl peroxide / further solvent(s) View Scheme

di-tert-butyl peroxide; triethylsilane in further solvent(s) byproducts: 1-hexene, (C2H5)3SiOSi(C2H5)3; Irradiation (UV/VIS); at 180 K, degassed soln. of compd. in C3H6 was photolyzed with di-tert-butyl peroxide, in the EPR cavity by light from 500 W superpressure Hg arc lamp for 5 h; detected by GC-MS;

di-tert-butyl peroxide in further solvent(s) byproducts: 1-hexene; Irradiation (UV/VIS); at 180 K, degassed soln. of compd. in C3H6 was photolyzed with di-tert-butyl peroxide, in the EPR cavity by light from 500 W superpressure Hg arc lamp; chromy.;

in diethyl ether T=-78 - 25°C;

in dichloromethane; pentane under N2; to soln. of B complex in CH2Cl2 added pentane, cooled to -10 °C, slowly added alcohol, stirred for 15 min; upper layer sepd., lower layer extd. with cold (0 °C) pentane, combined ext. evapd. in vac., distd.;

in tetrahydrofuran