in tetrahydrofuran at room temp.; further products; evapn. (vac.), reprecipitation from ether by heptane at -10°C; identification by mass spectroscopy;
参考文献
Journal of Organometallic Chemistry, , vol. 460, # 1 p. C6 - C7
UNIVERSITY OF NORTH CAROLINA AT CHAPEL HILL; GEORGIA STATE UNIVERSITY RESEARCH FOUNDATION, INC.
Patent: WO2005/40132 A1, 2005 ;
Location in patent: Page/Page column 48-50 ;
in tetrahydrofuran T=30°C; electron-transfer reaction between tert-butoxide ion and nitrobenzene; reaction in the presence of molecular oxygen, concentration dependence, isotope effect, mechanism; Product distributionRate constant;
参考文献
Guthrie, Robert D.; Nutter, Dale E.
Journal of the American Chemical Society, 1982 , vol. 104, # 26 p. 7478 - 7482