(CH3CH2)3N*3HF in N,N-dimethyl-formamide
byproducts: (CH3)3COH, KCl, KF; (Ar); stirring mixt. of 1 equiv. of copper chloride, 1.5-3 equiv. of potassium tert-butoxide, DMF and fluorobenzene as internal standart for 30 min at room temp., addn. of fluoroform, keeping for 5 min, addn. of triethylammonium deriv. in DMF; NMR monitoring;
参考文献
Zanardi, Alessandro; Novikov, Maxim A.; Martin, Eddy; Benet-Buchholz, Jordi; Grushin, Vladimir V.
Journal of the American Chemical Society, 2011 , vol. 133, # 51 p. 20901 - 20913
in N,N-dimethyl-formamide
byproducts: (CH3)3COH, KCl; (Ar); stirring mixt. of 1 equiv. of copper chloride, 1.5-3 equiv. of potassium tert-butoxide, DMF and fluorobenzene as internal standart for 30 min at room temp., addn. of fluoroform; NMR monitoring;
参考文献
Zanardi, Alessandro; Novikov, Maxim A.; Martin, Eddy; Benet-Buchholz, Jordi; Grushin, Vladimir V.
Journal of the American Chemical Society, 2011 , vol. 133, # 51 p. 20901 - 20913
in DMF-d7
byproducts: (CH3)3COH, KCl; (Ar); addn. of fluoroform to mixt. of copper chloride and potassium tert-butoxide in DMF-d7 at room temp.; NMR monitoring;
参考文献
Zanardi, Alessandro; Novikov, Maxim A.; Martin, Eddy; Benet-Buchholz, Jordi; Grushin, Vladimir V.
Journal of the American Chemical Society, 2011 , vol. 133, # 51 p. 20901 - 20913
Harjani, Jitendra R.; Abraham, Theodore J.; Gomez, Alwyn T.; Garcia, M. Teresa; Singer, Robert D.; Scammells, Peter J.
Green Chemistry, 2010 , vol. 12, # 4 p. 650 - 655
Glover, Stephen A.; Golding, Stephen L.; Goosen, Andre; McCleland, Cedric W.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1983 , # 10 p. 2479 - 2483
