in toluene Irradiation (UV/VIS); Ge-complex and Et3SiH were dissolved in toluene, photolyzed at -70°C for 16 h, CDCl3 was added under Ar; solvent was removed in vacuo, TLC on silica gel with CH2Cl2/hexane, recrystd. from hexane;
参考文献
Samuel, Mini S.; Jennings, Michael C.; Baines, Kim M.
Organometallics, 2001 , vol. 20, # 3 p. 590 - 592
Hoffmann, Harald M.; Draeger, Martin
Zeitschrift fuer Naturforschung, Teil B: Anorganische Chemie, Organische Chemie, 1986 , vol. 41, # 11 p. 1455 - 1460
in chloroform-d1
byproducts: bibenzyl, PhCH2CDCl2; Irradiation (UV/VIS); soln. of the stannane in CDCl3 was purged by N2 and irradiated with the light from an excimer laser (308 nm); mechanism of the photoreaction is proposed; (1)H NMR study;
参考文献
Standt, Adelheit; Dreeskamp, Herbert
Journal of Organometallic Chemistry, 1987 , vol. 322, p. 49 - 56
