1-(4-氯苯基)-2-(4-甲苯基)乙烷-1,2-二酮合成路线 （共 8 条）
反应条件
selenium(IV) oxide in dimethyl sulfoxide
0.0208333 h; microwave irradiation;
参考文献
Shirude; Patel; Giridhar; Yadav
Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 2006 , vol. 45, # 4 p. 1080 - 1085
反应条件
selenium(IV) oxide; toluene-4-sulfonic acid
T=30 - 35°C; 19 h; regioselective reaction;
参考文献
Rohman, Md. Rumum; Kharkongor, Icydora; Rajbangshi, Mantu; Mecadon, Hormi; Laloo, Badaker M.; Sahu, Priti R.; Kharbangar, Iadeishisha; Myrboh, Bekington
European Journal of Organic Chemistry, 2012 , # 2 p. 320 - 328
反应条件
1: SOCl2 / 3 h / Heating
2: AlCl3 / 0.75 h / 20 °C
3: 81 percent / SeO2 / dimethylsulfoxide / 0.01 h / microwave irradiation
View Scheme
参考文献
Ramajayam; Giridhar, Rajani; Yadav
Chemistry of Heterocyclic Compounds, 2006 , vol. 42, # 7 p. 901 - 906
反应条件
1: AlCl3 / 0.75 h / 20 °C
2: 81 percent / SeO2 / dimethylsulfoxide / 0.01 h / microwave irradiation
View Scheme
参考文献
Ramajayam; Giridhar, Rajani; Yadav
Chemistry of Heterocyclic Compounds, 2006 , vol. 42, # 7 p. 901 - 906
反应条件
1: 1.) n-BuLi / 1.) toluene, hexane, 15 min, 2.) toluene, hexane, 3 h
2: 62 percent / KMnO4, aq. MgSO4 / toluene / 50 h / 50 - 60 °C
View Scheme
参考文献
Aitken, R. Alan; Cadogan, J. I. G.; Gosney, Ian
Phosphorus, Sulfur and Silicon and the Related Elements, 1995 , vol. 101, # 1-4 p. 281 - 286
反应条件
1: 1.) n-BuLi / 1.) toluene, hexane, 15 min, 2.) toluene, hexane, 3 h
2: 62 percent / KMnO4, aq. MgSO4 / toluene / 50 h / 50 - 60 °C
View Scheme
参考文献
Aitken, R. Alan; Cadogan, J. I. G.; Gosney, Ian
Phosphorus, Sulfur and Silicon and the Related Elements, 1995 , vol. 101, # 1-4 p. 281 - 286
反应条件
1: Na(1+)*(SiMe3)2N(1-) / tetrahydrofuran / -60 °C
2: tetrahydrofuran / Ambient temperature
View Scheme
参考文献
Anders, Ernst; Clark, Timothy; Gassner, Thomas
Chemische Berichte, 1986 , vol. 119, # 4 p. 1350 - 1360
反应条件
hydrogenchloride; sodium hexamethyldisilazane
1) THF, 6 h, -30 deg C, 2) ether, r. t.; Yield given. Multistep reaction;
参考文献
Anders, Ernst; Gassner, Thomas
Angewandte Chemie, 1983 , vol. 95, # 8 p. 635
