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结构式
乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
86561-24-2
合成路线
(共 6 条)
86561-24-2
→
反应条件
22144-60-1
(R)-(+)-1-苯基-1-丁醇
+
22135-49-5
(S)-(-)-1-苯基-1-丁醇
反应条件
Rhizopus nigricans (sterile potato dextrose medium) in tetrahydrofuran 16 h; Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Ziffer, Herman; Kawai, Ken-ichi; Kasai, Masaji; Imuta, Mitsuru; Froussios, Cleanthis
Journal of Organic Chemistry, 1983 , vol. 48, # 18 p. 3017 - 3021
86561-24-2
→
反应条件
22144-60-1
(R)-(+)-1-苯基-1-丁醇
+
22135-49-5
(S)-(-)-1-苯基-1-丁醇
+
40628-81-7
+
84194-64-9
反应条件
4 A molecular sieve; lipase B (Candida antarctica, Novozym 435); 1-phenyl-2-methylethylamine in 1,4-dioxane T=30°C; 163 h; Enzymatic reaction; Product distribution; Further Variations:ReagentsSolventsratio;
参考文献
Garcia-Urdiales, Eduardo; Rebolledo, Francisca; Gotor, Vicente
Advanced Synthesis and Catalysis, 2001 , vol. 343, # 6-7 p. 646 - 654
86561-24-2
→
反应条件
22144-60-1
(R)-(+)-1-苯基-1-丁醇
反应条件
暂无反应条件数据
参考文献
Basavaiah; Raju
Synthetic Communications, 1991 , vol. 21, # 18-19 p. 1859 - 1863
86561-24-2
→
反应条件
22144-60-1
(R)-(+)-1-苯基-1-丁醇
+
22135-49-5
(S)-(-)-1-苯基-1-丁醇
反应条件
Rhizopus nigricans (sterile potato dextrose medium) in tetrahydrofuran 16 h; Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Ziffer, Herman; Kawai, Ken-ichi; Kasai, Masaji; Imuta, Mitsuru; Froussios, Cleanthis
Journal of Organic Chemistry, 1983 , vol. 48, # 18 p. 3017 - 3021
86561-24-2
→
反应条件
22144-60-1
(R)-(+)-1-苯基-1-丁醇
+
22135-49-5
(S)-(-)-1-苯基-1-丁醇
+
40628-81-7
+
84194-64-9
反应条件
4 A molecular sieve; lipase B (Candida antarctica, Novozym 435); 1-phenyl-2-methylethylamine in 1,4-dioxane T=30°C; 163 h; Enzymatic reaction; Product distribution; Further Variations:ReagentsSolventsratio;
参考文献
Garcia-Urdiales, Eduardo; Rebolledo, Francisca; Gotor, Vicente
Advanced Synthesis and Catalysis, 2001 , vol. 343, # 6-7 p. 646 - 654
86561-24-2
→
反应条件
22144-60-1
(R)-(+)-1-苯基-1-丁醇
+
22135-49-5
(S)-(-)-1-苯基-1-丁醇
+
40628-81-7
+
84194-64-9
反应条件
4 A molecular sieve; lipase B (Candida antarctica, Novozym 435); 1-phenyl-2-methylethylamine in 1,4-dioxane T=30°C; 163 h; Enzymatic reaction; Product distribution; Further Variations:ReagentsSolventsratio;
参考文献
Garcia-Urdiales, Eduardo; Rebolledo, Francisca; Gotor, Vicente
Advanced Synthesis and Catalysis, 2001 , vol. 343, # 6-7 p. 646 - 654