(4-溴苄氧基)三甲基硅烷合成路线 （共 13 条）
反应条件
2,2'-azo-bisisobutyronitrile; tri-n-butyl-tin hydride in benzene
T=80°C; 48 h;
参考文献
Nishiyama, Yutaka; Kajimoto, Hiroyuki; Kotani, Kazuya; Nishida, Takuma; Sonoda, Noboru
Journal of Organic Chemistry, 2002 , vol. 67, # 16 p. 5696 - 5700
反应条件
1: 4-Br-Ph-CH2OTMS With iodine; magnesium in tetrahydrofuran
T=20 - 85°C; 0.5 h;
2: 1-methoxy-allene With copper(I) bromide in tetrahydrofuran
T=0 - 20°C; 5 h;
3: With hydrogenchloride in water; ethyl acetate
参考文献
NOVARTIS AG; NOVARTIS PHARMA GMBH
Patent: WO2004/69256 A1, 2004 ;
Location in patent: Page/Page column 34 ;
WO 2004/069256 A1
反应条件
tetrachlorosilane; sodium iodide in acetonitrile
T=20°C; 1.5 h;
参考文献
Firouzabadi, Habib; Iranpoor, Nasser; Hazarkhani, Hassan
Tetrahedron Letters, 2002 , vol. 43, # 40 p. 7139 - 7141
