1-溴-3-甲基-2-丁烯合成路线 （共 689 条）
反应条件
1.1: NaH / tetrahydrofuran
1.2: 70 percent / n-(C4H9)Li / tetrahydrofuran
2.1: 82 percent / SnCl4 / CH2Cl2
View Scheme
参考文献
Sum,F.W.; Weiler,L.
Journal of the American Chemical Society, 1979 , vol. 101, p. 4401 - 4403
反应条件
(i) sBuLi, 9-BBN, (ii) /BRN= 1420778/; Multistep reaction;
参考文献
Yamamoto,Y. et al.
Journal of the Chemical Society, Chemical Communications, 1979 , p. 157 - 158
反应条件
1: dimethylformamide
2: HCl / CH2Cl2 / -78 °C
View Scheme
参考文献
Grob,C.A.; Waldner,A.
Helvetica Chimica Acta, 1979 , vol. 62, p. 1854 - 1865
反应条件
Merrifield resin supported tetra-alkyl ammonium azide in dimethyl amine
T=25°C; 72 h;
参考文献
Blass, Benjamin E.; Coburn, Keith R.; Faulkner, Amy L.; Seibel, William L.; Srivastava, Anil
Tetrahedron Letters, 2003 , vol. 44, # 10 p. 2153 - 2155
参考文献
Nishiyama, Kozaburo; Karigomi, Hiroshi
Chemistry Letters, 1982 , p. 1477 - 1478
反应条件
(i) Ni(CO)4, (ii) /BRN= 2594367/, (iii) aq. FeCl3; Multistep reaction;
参考文献
Sato; Inoue; Yamaguchi
The Journal of organic chemistry, 1972 , vol. 37, # 12 p. 1889 - 1892
反应条件
benzoylchlorobis(triphenylphosphine)palladium(II); zinc(II) chloride in tetrahydrofuran
T=65°C; 48 h;
参考文献
Godschalx, James; Stille, J. K.
Tetrahedron Letters, 1980 , vol. 21, p. 2599 - 2602
反应条件
benzoylchlorobis(triphenylphosphine)palladium(II) in benzene
T=100°C; 24 h;
参考文献
Godschalx, James; Stille, J. K.
Tetrahedron Letters, 1980 , vol. 21, p. 2599 - 2602
反应条件
titanium tetrachloride in dichloromethane
T=-78°C; 3 h;
参考文献
Hosomi, Akira; Imai, Takafumi; Endo, Masahiko; Sakurai, Hideki
Journal of Organometallic Chemistry, 1985 , vol. 285, p. 95 - 108
反应条件
benzoylchlorobis(triphenylphosphine)palladium(II); zinc(II) chloride
T=65°C; 24 h;
参考文献
Godschalx, James; Stille, J. K.
Tetrahedron Letters, 1980 , vol. 21, p. 2599 - 2602
