1-溴-3-甲基-2-丁烯合成路线 （共 689 条）
反应条件
triphenylphosphine; tris(dibenzylideneacetone)dipalladium(0) chloroform complex in benzene
60°C, 20 h; GLC;
参考文献
Kosugi, Masanori; Naka, Hiroyuki; Harada, Saburo; Sano, Hiroshi; Migita, Toshihiko
Chemistry Letters, 1987 , p. 1371 - 1372
反应条件
tris(dibenzylideneacetone)dipalladium(0) chloroform complex; triphenylphosphine in benzene
T=60°C; 20 h;
参考文献
Kosugi, Masanori; Naka, Hiroyuki; Harada, Saburo; Sano, Hiroshi; Migita, Toshihiko
Chemistry Letters, 1987 , p. 1371 - 1372
反应条件
1: 75 mg / 0.1N NaOH/MeOH / dimethylformamide / 3 h / Ambient temperature
2: 45 mg / dimethylsulfoxide / 3 h / 130 °C
3: 14 mg / diethyl ether / Ambient temperature
View Scheme
参考文献
Kikuchi, Tohru; Kadota, Shigetoshi; Matsuda, Satoko; Tanaka, Ken
Chemical & Pharmaceutical Bulletin, 1985 , vol. 33, # 5 p. 1969 - 1974
反应条件
1: 3-bromo-furan With n-butyllithium
2: prenyl bromide
参考文献
Tofi, Maria; Georgiou, Thomas; Montagnon, Tamsyn; Vassilikogiannakis, Georgios
Organic Letters, 2005 , vol. 7, # 15 p. 3347 - 3350
反应条件
n-butyllithium
Multistep reaction;
参考文献
Ullrich, John W.; Chiu, Fang-Ting; Tiner-Harding, Tammy; Mariano, Patrick S.
Journal of Organic Chemistry, 1984 , vol. 49, # 2 p. 220 - 228
反应条件
n-butyllithium
Multistep reaction;
参考文献
Ullrich, John W.; Chiu, Fang-Ting; Tiner-Harding, Tammy; Mariano, Patrick S.
Journal of Organic Chemistry, 1984 , vol. 49, # 2 p. 220 - 228
反应条件
Montmorillonite K10 clay in tetrachloromethane
2 h; Title compound not separated from byproducts;
参考文献
Dintzner, Matthew R.; McClelland, Kristen M.; Morse, Kara M.; Akroush, Michael H.
Synlett, 2004 , # 11 p. 2028 - 2030
反应条件
1: trans-crotonic acid With lithium diethylamide in tetrahydrofuran
T=0°C; 0.5 h;
2: prenyl bromide in tetrahydrofuran
T=20°C; 1 h;
参考文献
Domingo, Luis R.; Gil, Salvador; Parra, Margarita; Saez, Jose A.; Torres, Mercedes
Tetrahedron, 2003 , vol. 59, # 33 p. 6233 - 6239
反应条件
1: acetonitrile / 72 h / Ambient temperature
2: lithium di-isopropylamide (LDA) / tetrahydrofuran / 1 h / -40 °C
3: 90 percent / -78 - 25 °C
View Scheme
参考文献
Ousset, J.B.; Mioskowski, C.; Solladie, G.
Tetrahedron Letters, 1983 , vol. 24, # 41 p. 4419 - 4422
反应条件
1: acetonitrile / 72 h / Ambient temperature
2: lithium di-isopropylamide (LDA) / tetrahydrofuran / 1 h / -40 °C
3: 95 percent / -78 - 25 °C
View Scheme
参考文献
Ousset, J.B.; Mioskowski, C.; Solladie, G.
Tetrahedron Letters, 1983 , vol. 24, # 41 p. 4419 - 4422
