1: tBuCH2CH2B(H)NiPr2; PhN2BF4 With bis(cyclopentadienyl)titanium dichloride in acetonitrile T=20°C; 2.5 h; 2: With methanol in acetonitrile T=0 - 20°C; 1 h; 3: 2,3-dimethylbutane-2,3-diol in diethyl ether; acetonitrile T=20°C; 4 h; Reagent/catalyst;
参考文献
UNIVERSITE DE BORDEAUX 1; CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE; PUCHEAULT, Mathieu Jonathan Damien; MARCIASINI, Ludovic Daniel Alain; VAULTIER, Michel
Patent: WO2014/9169 A1, 2014 ;
Location in patent: Page/Page column 53-54; 67-68 ;
Silica-SMAP-Ir(OMe)(cod) in hexane T=50°C; 24 h; Autoclave; regioselective reaction;
参考文献
Kawamorita, Soichiro; Ohmiya, Hirohisa; Hara, Kenji; Fukuoka, Atsushi; Sawamura, Masaya
Journal of the American Chemical Society, 2009 , vol. 131, p. 5058 - 5059
silica-SMAP-Ir(OCH3)(C8H12) in hexane ligand reacted with B-compound in hexane in presence of Ir-complex as catalyst at 50°C for 24 h;
参考文献
Kawamorita, Soichiro; Ohmiya, Hirohisa; Hara, Kenji; Fukuoka, Atsushi; Sawamura, Masaya
Journal of the American Chemical Society, 2009 , vol. 131, p. 5058 - 5059
