9H-咔唑-2-基三氟甲烷磺酸酯合成路线 （共 6 条）
反应条件
tris-(dibenzylideneacetone)dipalladium(0); t-Bu Brett Phos; TDA; sodium nitrite in tert-butyl alcohol T=130°C; 24 h; regioselective reaction;
参考文献
Fors, Brett P.; Buchwald, Stephen L.
Journal of the American Chemical Society, 2009 , vol. 131, # 36 p. 12898 - 12899
反应条件
potassium fluoride; tris-(dibenzylideneacetone)dipalladium(0); t-Bu Brett Phos; potassium bromide in 1,4-dioxane T=130°C; 16 h; Inert atmosphere;
参考文献
Pan, Jun; Wang, Xinyan; Zhang, Yong; Buchwald, Stephen L.
Organic Letters, 2011 , vol. 13, # 18 p. 4974 - 4976
反应条件
in acetonitrile T=24.85°C; photo-Fries rearrangment; UV-irradiation; Product distribution; Further Variations:Solvents;
参考文献
Helvetica Chimica Acta, , vol. 89, # 6 p. 1147 - 1157
反应条件
1: 1,1'-bis-(diphenylphosphino)ferrocene; [Ni0(1,5-cyclooctadiene)2]; N,N-dicyclohexylmethylamine / 1,4-dioxane / 20 h / 100 °C / Inert atmosphere 2: hydrogenchloride / 1,4-dioxane; water / 1 h / 20 °C / Inert atmosphere View Scheme
参考文献
Gogsig, Thomas M.; Kleimark, Jonatan; Nilsson Lill, Sten O.; Korsager, Signe; Lindhardt, Anders T.; Norrby, Per-Ola; Skrydstrup, Troels
Journal of the American Chemical Society, 2012 , vol. 134, # 1 p. 443 - 452
反应条件
pyridine
T=20°C; 3 h;
参考文献
Crevatin, Laura K.; Bonesi, Sergio M.; Erra-Balsells, Rosa
Helvetica Chimica Acta, 2006 , vol. 89, # 6 p. 1147 - 1157
反应条件
potassium fluoride; tris-(dibenzylideneacetone)dipalladium(0); t-Bu Brett Phos; potassium chloride in 1,4-dioxane
T=130°C; 16 h; Inert atmosphere;
参考文献
Pan, Jun; Wang, Xinyan; Zhang, Yong; Buchwald, Stephen L.
Organic Letters, 2011 , vol. 13, # 18 p. 4974 - 4976
