1: With tri(n-octyl)aluminium in toluene T=80°C; 2: With CrCl3(THF)3; bis(di{ortho-methoxyphenyl}phosphanyl)(methyl)amine in toluene T=80°C; 1 h; Product distribution / selectivity;
1: With [(t-Bu)NP(Ph)2N(t-Bu)]Cr(μ2-Cl)2Li(THF)2 in toluene T=60°C; P=26252.6 Torr; 1 h; Inert atmosphere; 2: With hydrogenchloride in ethanol; toluene
diisobutylaluminium hydride; (dppf)Pd(0) in tetrahydrofuran T=-78 - 25°C; 24 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Journal of Organic Chemistry, , vol. 55, # 25 p. 6188 - 6194
