1,1-二氯-2,5-二氢硅杂环戊二烯合成路线 （共 38 条）
反应条件
in gas byproducts: butenyltrichlorogermane, trichlorogermyl 1,1-dichloro-1-silacyclopentane, chlorophenyltrichlorogermane; mixture passing through tubular quartz reactor, 550°C, 25-30 s, product yield depending on the amount of reactants; GLC of condensate;
参考文献
Russian Journal of General Chemistry, , vol. 67, # 11 p. 1722 - 1724
参考文献
Chernyshev,E.A. et al.
J. Gen. Chem. USSR (Engl. Transl.), 1978 , vol. 48, p. 830 - 838,757 - 763
反应条件
in gas byproducts: butenyltrichlorogermane, trichlorogermyl 1,1-dichloro-1-silacyclopentane, chlorophenyltrichlorogermane; mixture passing through tubular quartz reactor, 550°C, 25-30 s, product yield depending on the amount of reactants; GLC of condensate;
参考文献
Chernyshev; Komalenkova; Yakovleva; Bykovchenko; Khomykh; Bochkarev; Shcherbinin
Russian Journal of General Chemistry, 1997 , vol. 67, # 11 p. 1722 - 1724
反应条件
in gas byproducts: butenyltrichlorogermane, trichlorogermyl 1,1-dichloro-1-silacyclopentane, chlorophenyltrichlorogermane; mixture passing through tubular quartz reactor, 550°C, 25-30 s; GLC of condensate;
参考文献
Chernyshev; Komalenkova; Yakovleva; Bykovchenko; Khomykh; Bochkarev; Shcherbinin
Russian Journal of General Chemistry, 1997 , vol. 67, # 11 p. 1722 - 1724
反应条件
2,3-dimethyl-buta-1,3-diene T=550°C; half-reaction time; Rate constant;
参考文献
Ovchinnikov, I. V.; Golovkin, A. V.; Komalenkova, N. G.; Chernyshev, E. A.; Nikitin, V. S.
J. Gen. Chem. USSR (Engl. Transl.), 1987 , vol. 57, # 6 p. 1421 - 1422,1271 - 1272
反应条件
T=439 - 521°C; 0.00638889 h; kinetics, exchange reactions vs isomerization; MechanismRate constantProduct distribution;
参考文献
Chernyshev, E. A.; Bykovchenko, V. G.; Komalenkova, N. G.; Kiseleva, T. S.; Kel'man, M. Ya.
J. Gen. Chem. USSR (Engl. Transl.), 1992 , vol. 62, # 4.2. p. 838 - 841,691 - 693
反应条件
trichlorosilane; tetra-n-butyl phosphonium chloride
T=150°C; 2 h;
参考文献
Jung, II Nam; Yoo, Bok Ryul; Han, Joon Soo; Kang, Seung-Hyun
Patent: US2004/63983 A1, 2004 ;
Location in patent: Page 3 ;
反应条件
magnesium; ethylene dibromide in diethyl ether
40 h; Heating;
参考文献
Damrauer, Robert; Simon, Roger; Laporterie, Andre; Manuel, Georges; Tae Park, Young; Weber, William P.
Journal of Organometallic Chemistry, 1990 , vol. 391, # 1 p. 7 - 12
反应条件
1,1-dichloro-1-silacyclohexa-2,4-diene
T=560°C;
参考文献
Chernyshev, E. A.; Komalenkova, N. G.; Zagorets, D. A.; Kel'man, M. Ya.
J. Gen. Chem. USSR (Engl. Transl.), 1987 , vol. 57, # 12 p. 2732 - 2735,2437 - 2439
反应条件
anhydrous methyl chloride; copper(l) chloride; zinc(II) chloride; silicon
T=399.9°C; P=97.5 - 622.5 Torr; Further byproducts given;
参考文献
Okamoto, Masaki; Onodera, Satoshi; Okano, Tomoki; Suzuki, Eiichi; Ono, Yoshio
Journal of Organometallic Chemistry, 1997 , vol. 531, # 1-2 p. 67 - 71
