1,1-二氯-2,5-二氢硅杂环戊二烯合成路线 (共 38 条)
反应条件
copper(l) chloride; zinc(II) chloride; silicon
T=399.9°C; P=97.5 - 622.5 Torr; Further byproducts given;
参考文献
Okamoto, Masaki; Onodera, Satoshi; Okano, Tomoki; Suzuki, Eiichi; Ono, Yoshio
Journal of Organometallic Chemistry, 1997 , vol. 531, # 1-2 p. 67 - 71
反应条件
Si2Cl6; germanium tetrachloride
T=550°C; 0.00833333 h;
参考文献
Chernyshev; Komalenkova; Yakovleva; Bykovenko; Shcherbinin; Belokon'
Russian Journal of General Chemistry, 2001 , vol. 71, # 9 p. 1438 - 1442
参考文献
Chernyshev,E.A. et al.
Doklady Chemistry, 1972 , vol. 205, p. 642 - 644
Dokl. Akad. Nauk SSSR Ser. Khim., 1972 , vol. 205, p. 868 - 870
反应条件
T=300°C; Leiten ueber eine Silicium-Kupfer-Legierung;
参考文献
Petrow et al.
Zhurnal Obshchei Khimii, 1958 , vol. 28, p. 2085,2088;engl.Ausg.S.2122
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1955 , p. 947;engl.Ausg.S.861
反应条件
T=300°C; Leiten ueber eine Silicium-Kupfer-Legierung;
参考文献
Petrow et al.
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1955 , p. 947; engl. Ausg. S. 861
Zhurnal Obshchei Khimii, 1958 , vol. 28, p. 2085,2088; engl. Ausg. S. 2122, 2124
反应条件
T=550 - 600°C; Yield given;
参考文献
Chernyshev, E. A.; Komalenkova, N. G.; Kel'man, M. Ya.; Bochkarev, V. N.; Polivanov, A. N.; Zhun', V. I.
J. Gen. Chem. USSR (Engl. Transl.), 1988 , vol. 58, # 5 p. 1166 - 1167,1037 - 1038
反应条件
Si2Cl6
T=500°C; 0.00694444 h; other temperature 550 deg C; Product distributionMechanism;
参考文献
Chernyshev; Komalenkova; Kapitova; Bykovchenko; Khromykh; Bochkarev
Russian Journal of General Chemistry, 1996 , vol. 66, # 9 p. 1447 - 1450
反应条件
copper(l) chloride; zinc(II) chloride; silicon
T=399.9°C; P=240.02 - 480.04 Torr; reaction without butadiene; MechanismProduct distribution;
参考文献
Okamoto, Masaki; Onodera, Satoshi; Okano, Tomoki; Suzuki, Eiichi; Ono, Yoshio
Journal of Organometallic Chemistry, 1997 , vol. 531, # 1-2 p. 67 - 71
反应条件
T=560°C; Product distribution;
参考文献
Chernyshev, E. A.; Komalenkova, N. G.; Zagorets, D. A.; Kel'man, M. Ya.
J. Gen. Chem. USSR (Engl. Transl.), 1987 , vol. 57, # 12 p. 2732 - 2735,2437 - 2439
反应条件
T=580°C; 0.0111111 h; pulsed pyrolytic chromatography, effect of temperature, thermal decomposition of 1,1-dichloro-1-silacyclobutane in inert atmosphere and in the presence of butadiene, role of intemediates; Product distribution;
参考文献
Gusel'nikov, L. E.; Sokolova, V. M.; Volnina, E. A.; Kerzina, Z. A.; Nametkin, N. S.; et al.
Doklady Chemistry, 1981 , vol. 260, p. 409 - 411
Dokl. Akad. Nauk SSSR Ser. Khim., 1981 , vol. 260, # 2 p. 348 - 351