1,1-二氯-2,5-二氢硅杂环戊二烯合成路线 (共 38 条)
反应条件
chloroform; trichlorosilane
T=560°C; Addition; cycloaddition; Pyrolysis; Product distribution; Further Variations:Temperatures;
参考文献
Krasnova; Abramova; Alekseev; Chernyshev
Russian Chemical Bulletin, 1999 , vol. 48, # 10 p. 1960 - 1963
反应条件
silicon powder with ca. 4percent copper loading
T=291.9°C; Product distributionMechanism;
参考文献
Clarke, Michael P.; Davidson, Iain M. T.
Journal of Organometallic Chemistry, 1991 , vol. 408, # 2 p. 149 - 156
反应条件
T=564°C; thermal isomerization; KineticsThermodynamic data;
参考文献
Chernyshev, E. A.; Komalenkova, N. G.; Bykovchenko, V. G.; Kiseleva, T. S.; Kel'man, M. Ya.
J. Gen. Chem. USSR (Engl. Transl.), 1987 , vol. 57, # 6 p. 1270 - 1275,1137 - 1141
参考文献
Petrow et al.
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1955 , p. 947; engl. Ausg. S. 861
Zhurnal Obshchei Khimii, 1958 , vol. 28, p. 2085,2088; engl. Ausg. S. 2122, 2124
反应条件
in diethyl ether
2 h; Heating;
参考文献
Finkel'shtein, E. Sh.; Portnykh, E. B.; Ushakov, N. V.; Vdovin, V. M.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1981 , vol. 30, # 3 p. 483 - 487
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1981 , # 3 p. 641 - 645
参考文献
Petrow et al.
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1955 , p. 947; engl. Ausg. S. 861
Zhurnal Obshchei Khimii, 1958 , vol. 28, p. 2085,2088; engl. Ausg. S. 2122, 2124
参考文献
Chernyshev,E.A. et al.
J. Gen. Chem. USSR (Engl. Transl.), 1978 , vol. 48, p. 830 - 838,757 - 763
参考文献
Khabibullina,L.N. et al.
J. Gen. Chem. USSR (Engl. Transl.), 1978 , vol. 48, p. 2732 - 2737,2478 - 2482
反应条件
lithium aluminium tetrahydride in diethyl ether
2 h;
参考文献
Damrauer, Robert; Simon, Roger; Laporterie, Andre; Manuel, Georges; Tae Park, Young; Weber, William P.
Journal of Organometallic Chemistry, 1990 , vol. 391, # 1 p. 7 - 12
反应条件
potassium-sodium
T=320 - 350°C; P=0.1 - 1 Torr; in the presence of excess butadiene, other substrate; Product distribution;
参考文献
Gusel'nikov, L. E.; Volnina, E. A.; Kanevskii, A. B.; Komalenkova, N. G.; Kel'man, M. Ya.; Chernyshev, E. A.
J. Gen. Chem. USSR (Engl. Transl.), 1990 , vol. 60, # 2.2 p. 399 - 402,344 - 347