1.1: dicyclohexyl-carbodiimide; 1-hydroxy-pyrrolidine-2,5-dione / dichloromethane / 1 h / 20 °C 1.2: 1 h / 20 °C 1.3: 0.5 h 2.1: 1,8-diazabicyclo[5.4.0]undec-7-ene / N,N-dimethyl-formamide; acetonitrile / 0.25 h / 20 °C View Scheme
(batho)2CuII (batho = 2,9-dimethyl-4,7-diphenyl-1,10-phenanthrolinedisulfonate); water T=25°C; 24 h; pH 8; var. reaction time and amine concentration; other aliphatic amines; Rate constantProduct distributionMechanism;
参考文献
Journal of the American Chemical Society, , vol. 114, # 1 p. 248 - 255
