hydrogen; palladium in acetic acid T=20°C; Catalytic hydrogenation; 6 h;

1: Geotrichum candidum IFO 4597 / H2O / 24 h / 30 °C / Microbiological reaction 2: 87 percent / H2 / Pd black / acetic acid / 6 h / 20 °C View Scheme

[{(η5-C5Me5)RhCl}2(μ-Cl)2]; 3,3'-[(1R,2R)-1-amino-2-(4-dodecylphenylsulfonamido)ethane-1,2-diyl]bis(N,N,N-trimethylbenzenaminium)diiodide; sodium formate in water T=5°C; 24 h; enantioselective reaction;

[Al(OsBu)3] weitgehend racemisches Praeparat;

Geotrichum candidum IFO 4597 in water T=30°C; Reduction; 24 h; Microbiological reaction; Product distribution; Further Variations:Reagents;