1: triphenylphosphine / chlorotris(triphenylphosphine)rhodium / tetrahydrofuran; propan-2-ol / 25 °C 2: 0.148 g / H2 / chlorotris(triphenylphosphine)rhodium / propan-2-ol; tetrahydrofuran / 12 h / 25 °C / 5320 Torr View Scheme

nonafluoro-n-butanesulfonyl fluoride; phosphazene base P1-t-bu-tris(tetramethylene) in N,N-dimethyl-formamide T=-30 - 20°C; Inert atmosphere; chemoselective reaction;

RuCl(Ph3P)3; triphenylphosphine in tetrahydrofuran; isopropyl alcohol T=25°C; 0.5 h;

sodium hexamethyldisilazane in tetrahydrofuran

MoOCl3(THF)2 multistep reaction; competition reactions of different carbonyl compounds, chemoselectivity; Product distribution;