1: C8H5Br2NO3 With tetrabutyl ammonium fluoride in N,N-dimethyl-formamide
T=20°C; 4 h; Sealed tubeInert atmosphere;
2: benzenesulphinic acid sodium salt With copper diacetate; triethylamine; palladium dichloride in N,N-dimethyl-formamide
T=110°C; 12 h; Sealed tubeInert atmosphere;
参考文献
Chen, Wei; Li, Pinhua; Miao, Tao; Meng, Ling-Guo; Wang, Lei
Organic and Biomolecular Chemistry, 2013 , vol. 11, # 3 p. 420 - 424
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反应条件
1,1'-bis-(diphenylphosphino)ferrocene; [14C]-Tetramethylammonium bromide; bis(η3-allyl-μ-chloropalladium(II)) in dichloromethane; water
T=20°C; 2.5 h; Title compound not separated from byproducts;
参考文献
Trost, Barry M.; Machacek, Michelle R.; Tsui, Hong C.
Journal of the American Chemical Society, 2005 , vol. 127, # 19 p. 7014 - 7024
1: 1-(4-methoxyphenyl)ethanone With (hydroxy(tosyloxy)iodo)benzene in acetonitrile
0.666667 h; Heating;
2: benzenesulphinic acid sodium salt in water; acetonitrile
2 h; Heating;
