1: With trimethylsilyl trifluoromethanesulfonate; benzo[1,3,2]dioxaborole; [Rh(acac)(COD)]2; (R)-1-(2-phenylquinazolin-4-yl)-2-(Ph2P)-naphthalene in tetrahydrofuran T=25°C; Addition; Hydroboration; 2 h; 2: With sodium hydroxide; dihydrogen peroxide in tetrahydrofuran T=20°C; Oxidation; Hydrolysis; 1 h; Further stages. Title compound not separated from byproducts.;
参考文献
Fleming, William J.; Mueller-Bunz, Helge; Guiry, Patrick J.
European Journal of Organic Chemistry, 2010 , # 31 p. 5996 - 6004
1: With iodine; borane-pyridine complex in dichloromethane T=20°C; 2 h; 2: With sodium hydroxide; dihydrogen peroxide in methanol; dichloromethane T=0 - 20°C; Title compound not separated from byproducts;
参考文献
Lillo, Vanesa; Mata, Jose A.; Segarra, Anna M.; Peris, Eduardo; Fernandez, Elena
Chemical Communications, 2007 , # 21 p. 2184 - 2186
1: With CF3O3S(1-)*C45H39N2OPRh(1+); benzo[1,3,2]dioxaborole in tetrahydrofuran T=20°C; Inert atmosphere; 2: With dihydrogen peroxide; sodium hydroxide in ethanol; water T=0 - 20°C; optical yield given as percent eeenantioselective reaction;
参考文献
Maxwell, Aoife C.; Flanagan, Susan P.; Goddard, Richard; Guiry, Patrick J.
Tetrahedron Asymmetry, 2010 , vol. 21, # 11-12 p. 1458 - 1473
