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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
对氯苯乙炔
合成路线
(共 125 条)
873-73-4
对氯苯乙炔
+
95-54-5
1,2-苯二胺
→
反应条件
89586-98-1
反应条件
(2-biphenyl)Cy2PAuNTf2 in chloroform T=60°C; 6 h;
参考文献
Qian, Jianqiang; Liu, Yunkui; Cui, Jianhai; Xu, Zhenyuan
Journal of Organic Chemistry, 2012 , vol. 77, # 9 p. 4484 - 4490
873-73-4
对氯苯乙炔
→
反应条件
89619-10-3
1-(1-溴乙烯基)-4-氯苯
反应条件
hydrogen bromide in acetic acid
参考文献
Gassman, Paul G.; Harrington, Clinton K.
Journal of Organic Chemistry, 1984 , vol. 49, # 12 p. 2258 - 2273
873-73-4
对氯苯乙炔
→
反应条件
66482-29-9
+
89619-10-3
1-(1-溴乙烯基)-4-氯苯
反应条件
hydrogen bromide; bromide; trifluoroacetic acid in dichloromethane Kinetics;
参考文献
Weiss, Hilton M.; Touchette, Kim M.; Angell, Sarah; Khan, Jihan
Organic and Biomolecular Chemistry, 2003 , vol. 1, # 12 p. 2152 - 2156
873-73-4
对氯苯乙炔
→
反应条件
89891-82-7
反应条件
4-(N,N-dimethlyamino)pyridine; iodine in dichloromethane 6 h; Heating;
参考文献
Meng, Ling-Guo; Cai, Pei-Jie; Guo, Qing-Xiang; Xue, Song
Synthetic Communications, 2008 , vol. 38, # 2 p. 225 - 231
873-73-4
对氯苯乙炔
+
7154-66-7
2-溴苯甲酰氯
→
反应条件
919481-49-5
反应条件
1: bromobenzoic acid chloride With tetrakis(triphenylphosphine) palladium(0); triethylamine in tetrahydrofuran T=20°C; Sonogashira cross-coupling; Inert atmosphere; 2: With copper(l) iodide in tetrahydrofuran T=20°C; Sonogashira cross-coupling; Inert atmosphere; 3: 1-chloro-4-ethynylbenzene in tetrahydrofuran T=20°C; Sonogashira cross-coupling; Inert atmosphere;
参考文献
Bernini, Roberta; Cacchi, Sandro; Fabrizi, Giancarlo; Sferrazza, Alessio
Synthesis, 2009 , # 7 art. no. Z26108SS, p. 1209 - 1219
923026-24-8
+
873-73-4
对氯苯乙炔
→
反应条件
923026-44-2
反应条件
1: 1-chloro-4-ethynylbenzene With n-butyllithium in tetrahydrofuran; hexane T=-78°C; 0.25 h; 2: N-methyl-N-methoxy-2-[(3-phenylprop-2-yn-1-yl)oxy]acetamide in tetrahydrofuran; hexane T=-78 - 20°C;
参考文献
Wessig, Pablo; Mueller, Gunnar; Herre, Robert; Kuehn, Andreas
Helvetica Chimica Acta, 2006 , vol. 89, # 11 p. 2694 - 2719
75-21-8
环氧乙烷
+
873-73-4
对氯苯乙炔
→
反应条件
52999-16-3
反应条件
N,N,N',N',N'',N''-hexamethylphosphoric triamide; lithium in benzene
参考文献
Shevchenko,Z.A. et al.
Journal of Organic Chemistry USSR (English Translation), 1974 , vol. 10, p. 957 - 959
Zhurnal Organicheskoi Khimii, 1974 , vol. 10, # 5 p. 946 - 948
873-73-4
对氯苯乙炔
→
反应条件
62440-19-1
反应条件
n-butyllithium in diethyl ether T=0°C; 0.25 h;
参考文献
Gifu University
Patent: US2004/167346 A1, 2004 ;
Location in patent: Page 4 ;
873-73-4
对氯苯乙炔
+
5153-67-3
反式-β-硝基苯乙烯
→
反应条件
6273-42-3
反应条件
1: 1-chloro-4-ethynylbenzene With aminobenzyl Wang resin; mercury(II) diacetate; diisopropylamine in tetrahydrofuran; dichloromethane T=20°C; Solid phase reaction; amination; 72 h; 2: (trans)-β-nitrostyrene in dichloromethane Solid phase reaction; addition; 6 h; 3: With trifluoroacetic acid in dichloromethane Solid phase reaction; hydrolysis; 0.333333 h;
参考文献
Aznar, Fernando; Valdes, Carlos; Cabal, Maria-Paz
Tetrahedron Letters, 2000 , vol. 41, # 30 p. 5683 - 5687
873-73-4
对氯苯乙炔
→
反应条件
反应条件
bis(allyl)-ruthenium(IV) dimer in methanol; water T=75°C; 1 h;
参考文献
Cadierno, Victorio; Garcia-Garrido, Sergio E.; Gimeno, Jose
Journal of the American Chemical Society, 2006 , vol. 128, # 47 p. 15094 - 15095
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