3,3,5-三甲基环己酮合成路线 （共 69 条）
反应条件
p-mentha-1,8-diene; Pd-BaSO4 0.5 h; Heating;
参考文献
Mhadgut, Shilpa C.; Palaniappan, Kumaranand; Thimmaiah, Muralidhara; Hackney, Stephen A.; Toeroek, Bela; Liu, Jian
Chemical Communications, 2005 , # 25 p. 3207 - 3209
反应条件
3β,17β-dihydroxy-17α-methylandrost-5-ene in diethyl ether; hexane; toluene T=-78°C;
参考文献
Maruoka, Keiji; Itoh, Takayuki; Sakurai, Minoru; Nonoshita, Katsumasa; Yamamoto, Hisashi
Journal of the American Chemical Society, 1988 , vol. 110, p. 3588 - 3597
反应条件
NiCRASi in tetrahydrofuran T=45°C; 0.75 h;
参考文献
Fort, Y; Vanderesse, R; Caubere, P
Tetrahedron Letters, 1986 , vol. 27, # 45 p. 5487 - 5490
反应条件
imidazolium dichromate in N,N-dimethyl-formamide 24 h; Ambient temperature;
参考文献
Kim, Sunggak; Lhim, Dong Chul
Bulletin of the Chemical Society of Japan, 1986 , vol. 59, p. 3297 - 3298
反应条件
tert.-butylhydroperoxide; 3 A molecular sieve; 3,3,5c-trimethyl-cyclohexan-r-ol; zirconium tetra-n-propoxide in dichloromethane T=20°C; 7 h;
参考文献
Journal of Organic Chemistry, , vol. 61, # 4 p. 1467 - 1472
反应条件
tert.-butylhydroperoxide; 3 A molecular sieve; trans-3,3,5-trimethylcyclohexanone; zirconium tetra-n-propoxide in dichloromethane T=20°C; 7 h;
参考文献
Journal of Organic Chemistry, , vol. 61, # 4 p. 1467 - 1472
反应条件
hydrogen; palladium 10 on activated carbon T=220°C; P=749.884 Torr; 6 h; Product distribution / selectivity;
参考文献
WO2009/85826 A2, ;
Page/Page column 8 ;
反应条件
hydrogen; 5-palladium/activated carbon T=225°C; P=2585.81 Torr; 22 h; Product distribution / selectivity;
参考文献
WO2009/85826 A2, ;
Page/Page column 7 ;
反应条件
ATPH; n-butyllithium; diisobutylaluminium hydride 1) toluene, -78 deg C; 2) toluene, THF, hexane, -78 deg C, 15 min; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Journal of Organic Chemistry, , vol. 61, # 9 p. 2928 - 2929
反应条件
iron nitrate (III) in dichloromethane 30 min., r.t., then reflux;
参考文献
Laszlo, Pierre; Polla, Eugenio
Tetrahedron Letters, 1984 , vol. 25, # 31 p. 3309 - 3312
