2-(4,4,5,5-四甲基-1,3,2-二噁硼烷-2-基)-5-(三氟甲基)苯甲酸甲酯合成路线 （共 2 条）
反应条件
potassium acetate; tris-(dibenzylideneacetone)dipalladium(0); tri-cyclo-hexyl-phosphine in 1,4-dioxane
T=20 - 80°C; 20 h;
参考文献
NOVARTIS AG; NOVARTIS PHARMA GMBH
Patent: WO2006/136442 A1, 2006 ;
Location in patent: Page/Page column 90-91 ;
WO 2006/136442 A1
反应条件
[Ir(OMe)(COD)]2/tris[3,5-bis(CF3)phenyl]phosphine in octane
80°C, 16 h, benzoate ester (5.0 mmol), bis(pinacolato)diboron (1.0 mmol), (Ir(OMe)(COD))2 (0.015 mmol), tris(3,5-bis(trifluoromethyl)phenyl)phosphine (0.06 mmol);
参考文献
Ishiyama, Tatsuo; Isou, Hironori; Kikuchi, Takao; Miyaura, Norio
Chemical Communications, 2010 , vol. 46, # 1 p. 159 - 161
