N,N-二甲基苯胺氧化物合成路线 （共 73 条）
参考文献
Walter
Chem. Zentralbl., 1911 , vol. 82, # I p. 879
参考文献
Bamberger; Leyden
Chemische Berichte, 1901 , vol. 34, p. 12
Full Text Show Details
Bamberger; Tschirner
Chemische Berichte, 1899 , vol. 32, p. 346,1890
反应条件
1: CH2Cl2 / 0.5 h / 0 °C
2: 1.) methyllithium / 1.) THF, 0 deg C, 1 h; 2.) THF, RT, overnight
View Scheme
参考文献
Okazaki, Renji; Tokitoh, Norihiro
Journal of the Chemical Society, Chemical Communications, 1984 , # 3 p. 192 - 193
反应条件
trifluoroacetic acid; trifluoroacetic anhydride in benzene
T=30°C;
参考文献
Shudo, Koichi; Ohta, Toshiharu; Okamoto, Toshihiko
Journal of the American Chemical Society, 1981 , vol. 103, # 3 p. 645 - 653
反应条件
water; anhydrous sulfurous acid
T=0°C;
参考文献
Bamberger; Tschirner
Chemische Berichte, 1899 , vol. 32, p. 1883,1893
反应条件
water
dann mit wss.-methanol.KOH;
参考文献
Huisgen et al.
Chemische Berichte, 1959 , vol. 92, p. 3223,3236
反应条件
trifluoroacetic acid; trifluoroacetic anhydride in benzene
T=30°C;
参考文献
Shudo, Koichi; Ohta, Toshiharu; Okamoto, Toshihiko
Journal of the American Chemical Society, 1981 , vol. 103, # 3 p. 645 - 653
反应条件
trifluorormethanesulfonic acid
1.) 0 deg C, 1 h, 2.) room temperature, 4 h;
参考文献
Shudo, Koichi; Ohta, Toshiharu; Okamoto, Toshihiko
Journal of the American Chemical Society, 1981 , vol. 103, # 3 p. 645 - 653
反应条件
in acetonitrile
0.0833333 h; other olefines, N-oxides of amines, with water or with N,N-dimethylanline, var. temp., solv.; Product distributionMechanism;
参考文献
Zipplies, Matthias F.; Vos, Marie-Joelle De; Bruice, Thomas C.
Journal of Organic Chemistry, 1985 , vol. 50, # 17 p. 3228 - 3230
反应条件
DAL in tetrahydrofuran
T=-78°C;
参考文献
Beugelmans, Rene; Benadjila-Iguertsira, Leila; Chastanet, Jacqueline; Negron, Guillermo; Roussi, Georges
Canadian Journal of Chemistry, 1985 , vol. 63, p. 725 - 734
