(5S)-3-[(E)-{(1R,7aR)-1-[(2R,3E,5R)-5,6-二甲基-3-庚烯-2-基]-7a-甲基八氢-4H-茚-4-亚基}甲基]-1,3,4,5,6,7-六氢-2-苯并噻吩-5-醇2,2-二氧化物合成路线 （共 2 条）
87407-73-6(5S)-3-[(E)-{(1R,7aR)-1-[(2R,3E,5R)-5,6-二甲基-3-庚烯-2-基]-7a-甲基八氢-4H-茚-4-亚基}甲基]-1,3,4,5,6,7-六氢-2-苯并噻吩-5-醇2,2-二氧化物
→
反应条件
1: NaHCO3 / ethanol / Heating 2: imidazole / dimethylformamide 3: SeO2, N-methylmorpholine N-oxide / methanol; CH2Cl2 / Heating 4: acridine / Irradiation 5: (C4H9)4N1+*F1- / tetrahydrofuran View Scheme
参考文献
Andrews; Barton; Cheng; et al.
Journal of Organic Chemistry, 1986 , vol. 51, # 9 p. 1635 - 1637
87407-73-6(5S)-3-[(E)-{(1R,7aR)-1-[(2R,3E,5R)-5,6-二甲基-3-庚烯-2-基]-7a-甲基八氢-4H-茚-4-亚基}甲基]-1,3,4,5,6,7-六氢-2-苯并噻吩-5-醇2,2-二氧化物
→
反应条件
1: NaHCO3 / ethanol / Heating 2: imidazole / dimethylformamide 3: SeO2, N-methylmorpholine N-oxide / methanol; CH2Cl2 / Heating 4: acridine / Irradiation 5: (C4H9)4N1+*F1- / tetrahydrofuran View Scheme
参考文献
Andrews; Barton; Cheng; et al.
Journal of Organic Chemistry, 1986 , vol. 51, # 9 p. 1635 - 1637
