in benzene T=600°C; 0.00305556 h; in a quartz pulse microreactor; various reaction temperatures; Product distributionMechanism;

in benzene T=600°C; 0.00305556 h; in a quartz pulse microreactor; various reaction temperatures; Product distributionMechanism;

sulfur; dodecacarbonyltriiron in benzene T=55°C; 8 h;

sulfur; dodecacarbonyltriiron in benzene T=55°C; 8 h;

in benzene byproducts: 1,4-di(trimethylsilyl)-2,3,6,7-tetrathiacyclooctan, 1-methyl-3-trimethylsilyl-2,5-dithiacyclopentane; mixt. of educts in benzene stirred at 55°C for 8 h; evapd. in vac., extd. with pentane, evapd., chromd. (SiO2, hexane);

in benzene byproducts: Me3SiCHCH2SCH2CH(SiMe3)S2, Me3SiCHCH2S2CH2CH(SiMe3)S2; mixt. of educts in benzene stirred at 55°C for 8 h; evapd. in vac., extd. with pentane, evapd., chromd. (SiO2, hexane), dissolved in benzene, refluxed with stirring for 4 h, evapd., crystd. from ethanol, recrystd. from hexane; elem. anal.;

in benzene T=600°C; 0.00305556 h; in a quartz pulse microreactor; various reaction temperatures; Product distributionMechanism;

in further solvent(s) byproducts: CO; stirring a mixt. of the polysulfide and Fe3(CO)12 in trimethylvinylsilane at 55°C for 2 h; filtn., washing the ppt. with hot benzene, evapn. of the solvents from the filtrate, column chromy. on silica gel (hexane);

in further solvent(s) byproducts: CO; stirring a mixt. of the polysulfide and Fe3(CO)12 in trimethylvinylsilane at 55°C for 2 h; filtn., washing the ppt. with hot benzene, evapn. of the solvents from the filtrate, column chromy. on silica gel (hexane);