2-甲基-1,3-茚满二酮合成路线 （共 31 条）
反应条件
1: methanol
2: HCl / ethanol
View Scheme
参考文献
Allisson,S. et al.
Helvetica Chimica Acta, 1970 , vol. 53, p. 809 - 813
反应条件
1: Br2 / CHCl3 / Irradiation
2: methanol
3: HCl / ethanol
View Scheme
参考文献
Allisson,S. et al.
Helvetica Chimica Acta, 1970 , vol. 53, p. 809 - 813
反应条件
sulfuric acid
T=100°C;
参考文献
Simonis; Wojack
Chemische Berichte, 1937 , vol. 70, p. 1837,1846
反应条件
silica gel
other reagents: neutralaluminia or Florisil;
参考文献
Schultz, Arthur G.; McMahon, Wayne G.
Journal of Organic Chemistry, 1984 , vol. 49, # 9 p. 1676 - 1678
参考文献
Nathanson
Chemische Berichte, 1893 , vol. 26, p. 2582
反应条件
sodium methylate in methanol; dimethyl sulfoxide
T=30°C; effect of pre-equilibrium; correlation with the acidity function, effect of DMSO content in MeOH, kinetic isotope effect; Rate constant;
参考文献
Bowden, Keith; Chehel-Amiran, Mohsen
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1986 , p. 2035 - 2038
反应条件
sodium methylate in methanol; dimethyl sulfoxide
T=30°C; effect of pre-equilibrium; correlation with the acidity function, effect of DMSO content in MeOH, kinetic isotope effect; Rate constant;
参考文献
Bowden, Keith; Chehel-Amiran, Mohsen
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1986 , p. 2035 - 2038
参考文献
Mowry et al.
Journal of the American Chemical Society, 1949 , vol. 71, p. 120
反应条件
n-butyllithium in tetrahydrofuran; hexane
1 h; Ambient temperature;
参考文献
Benati, Luisa; Montevecchi, Pier Carlo; Spagnolo, Piero; Foresti, Elisabetta
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1992 , # 21 p. 2845 - 2850
反应条件
toluene, 100 deg C, 17 h; Yield given. Multistep reaction. Further byproducts given. Yields of byproduct given;
参考文献
Benati, Luisa; Montevecchi, P. Carlo; Spagnolo, Piero
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1991 , # 1 p. 71 - 77
