2,4,6-三甲基苯胺合成路线 （共 254 条）
反应条件
copper diacetate in dichloromethane
3.5 h; Ambient temperature;
参考文献
Barton, Derek H. R.; Yadav-Bhatnagar, Neerja; Finet, Jean-Pierre; Khamsi, Jamal
Tetrahedron Letters, 1987 , vol. 28, # 27 p. 3111 - 3114
反应条件
copper in dichloromethane
0.75 h; Ambient temperature;
参考文献
Barton, Derek H. R.; Finet, Jean-Pierre; Khamsi, Jamal
Tetrahedron Letters, 1986 , vol. 27, # 31 p. 3615 - 3618
反应条件
in N,N-dimethyl-formamide
T=130°C; 24 h;
参考文献
Carroll, Michael A.; Wood, Reice A.
Tetrahedron, 2007 , vol. 63, # 46 p. 11349 - 11354
反应条件
(1,3-bis(2,6-diisopropylphenyl)imidazolidene)Ni(styrene)2; lithium tert-butylate in 1,4-dioxane
10 h; Inert atmosphereHeatingSchlenk technique;
参考文献
Iglesias, Maria Jose; Blandez, Juan F.; Fructos, Manuel R.; Prieto, Auxiliadora; Alvarez, Eleuterio; Belderrain, Tomas R.; Nicasio, M. Carmen
Organometallics, 2012 , vol. 31, # 17 p. 6312 - 6316
反应条件
copper diacetate in dichloromethane
20 h; Ambient temperatureunder argon;
参考文献
Barton, Derek H. R.; Finet, Jean-Pierre; Khamsi, Jamal
Tetrahedron Letters, 1987 , vol. 28, # 8 p. 887 - 890
反应条件
Cu(II) pivalate in dichloromethane
0.0833333 h; Ambient temperatureother BiV reagents; copper-catalyzed phenylation of amines by BiV reagents; Product distribution;
参考文献
Arnauld, Thomas; Barton, Derek H.R.; Doris, Eric
Tetrahedron, 1997 , vol. 53, # 12 p. 4137 - 4144
反应条件
lead(IV) acetate; chloroform
参考文献
Wessely et al.
Monatshefte fuer Chemie, 1955 , vol. 86, p. 831,844
反应条件
1: benzoic acid With sodium azide; phenyl chloroformate; sodium t-butanolate in ethylene glycol dimethyl ether
T=25°C; 8 h;
2: 2,4,6-trimethylbenzenamine in ethylene glycol dimethyl ether
T=75°C; 16 h;
参考文献
Lebel, Helene; Leogane, Olivier
Organic Letters, 2006 , vol. 8, # 25 p. 5717 - 5720
参考文献
Grammaticakis
Bulletin de la Societe Chimique de France, 1949 , p. 761,764
Bulletin de la Societe Chimique de France, 1968 , p. 1057,1059
反应条件
1.1: aq. methanol / 16 h / 20 °C
2.1: aq. NH4Cl / methanol / 1 h / Heating
2.2: aq. H3PO4 / methanol / Heating
View Scheme
参考文献
Liu, Jingping; Chen, Jingbo; Zhao, Jingfeng; Zhao, Yuanhong; Li, Liang; Zhang, Hongbin
Synthesis, 2003 , # 17 p. 2661 - 2666
