2,4,6-三甲基苯胺合成路线 （共 254 条）
反应条件
triethylamine in dichloromethane
12 h; Heating;
参考文献
Barcock, Richard A.; Chadwick, Derek J.; Storr, Richard C.; Fuller, Lance S.; Young, John H.
Tetrahedron, 1994 , vol. 50, # 14 p. 4149 - 4166
反应条件
copper(I) pivalate in benzene
1 h; Ambient temperature; Yield given. Yields of byproduct given;
参考文献
Barton, Derek H.R.; Doris, Eric
Tetrahedron Letters, 1996 , vol. 37, # 19 p. 3295 - 3298
反应条件
1.1: hydrogenchloride / water / Cooling with ice
1.2: 0.83 h / -5 °C
1.3: 76 h / 20 °C
2.1: copper(l) iodide; tetrakis(triphenylphosphine) palladium(0); diisopropylamine / tetrahydrofuran / 17 h / 50 °C / Inert atmosphere
3.1: sodium hydroxide / methanol / 4 h / 20 °C / Inert atmosphere
3.2: Inert atmosphere
View Scheme
参考文献
Kloss, Florian; Koehn, Uwe; Jahn, Burkhard O.; Hager, Martin D.; Goerls, Helmar; Schubert, Ulrich S.
Chemistry - An Asian Journal, 2011 , vol. 6, # 10 p. 2816 - 2824
参考文献
Grillot; Schaffrath
Journal of Organic Chemistry, 1959 , vol. 24, p. 1035,1036
反应条件
choline chloride*2SnCl2
T=70°C;
参考文献
Azizi, Najmadin; Gholibeglo, Elham; Babapour, Mahbobe; Ghafuri, Hossein; Bolourtchian, Seyed Mohammad
Comptes Rendus Chimie, 2012 , vol. 15, # 9 p. 768 - 773
反应条件
choline chloride*2SnCl2 in water
T=70°C;
参考文献
Azizi, Najmadin; Gholibeglo, Elham; Babapour, Mahbobe; Ghafuri, Hossein; Bolourtchian, Seyed Mohammad
Comptes Rendus Chimie, 2012 , vol. 15, # 9 p. 768 - 773
反应条件
T=200°C; 12 h; Autoclave;
参考文献
BASF SE; BASF (CHINA) COMPANY LIMITED; HASHMI, A., Stephen K.; LOTHSCHUeTZ, Christian
Patent: WO2012/56419 A1, 2012 ;
Location in patent: Page/Page column 63 ;
反应条件
phenyl silane; C{N(2,6-iPr2C6H3)CH}2 in tetrahydrofuran
T=20°C; P=750.075 Torr; 24 h; Inert atmosphere;
参考文献
Jacquet, Olivier; Das Neves Gomes, Christophe; Ephritikhine, Michel; Cantat, Thibault
Journal of the American Chemical Society, 2012 , vol. 134, # 6 p. 2934 - 2937
反应条件
hydrogenchloride
T=250°C; P=2206520 Torr;
参考文献
Buckley; Ray
Journal of the Chemical Society, 1949 , p. 1154
反应条件
T=250°C; P=2206520 Torr;
参考文献
Buckley; Ray
Journal of the Chemical Society, 1949 , p. 1154
