in water T=24.7°C; effect of concn of various strong acid catalysts (HCl, HNO3, HClO4, H2SO4), carboxylic acids, effect of temp.; Rate constantMechanismProduct distribution;
参考文献
Senogles, Ernest; Thomas, Roderick A.
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1980 , p. 825 - 828
1: With 2,9-dimethyl-1,10-phenanthroline; p-benozquinone; palladium diacetate in acetonitrile T=100°C; Heck reaction; 0.166667 h; microwave irradiation; 2: With silica gel in ethyl acetate Further stages.;
参考文献
Journal of Organic Chemistry, , vol. 72, # 21 p. 7957 - 7962
1: With 4-methyl-morpholine; 2,9-dimethyl-1,10-phenanthroline; oxygen; palladium diacetate in various solvent(s) T=80°C; Heck arylation reaction; 1.16667 h; microwave irradiation; 2: With hydrogenchloride; water in various solvent(s) 1 h; Title compound not separated from byproducts;
参考文献
Journal of Organic Chemistry, , vol. 69, # 16 p. 5212 - 5218
in melt stirring of triphenyltin hydride and N-vinylpyrrolidin-2-one at 90°C for 4 h as a melt under N2;; recrystallization from petroleum ether yields hexaphenylditin; evaporation of the mother liquor to dryness under reduced pressure; recrystallization from petroleum ether; elem. anal.;;
1: With 4-methyl-morpholine; 2,9-dimethyl-1,10-phenanthroline; oxygen; palladium diacetate in various solvent(s) T=50°C; Heck arylation reaction; 18 h; 2: With hydrogenchloride; water
参考文献
Andappan, Murugaiah M. S.; Nilsson, Peter; Von Schenck, Henrik; Larhed, Mats
Journal of Organic Chemistry, 2004 , vol. 69, # 16 p. 5212 - 5218
