bis-triphenylphosphine-palladium(II) chloride; N-ethyl-N,N-diisopropylamine; triphenylphosphine in tetrahydrofuran T=110°C; P=7600.51 Torr; 20 h; Autoclave;

bis-triphenylphosphine-palladium(II) chloride; N-ethyl-N,N-diisopropylamine; triphenylphosphine in tetrahydrofuran T=110°C; P=7600.51 Torr; 24 h; Autoclave;

1.1: bromo-dimethylsulfonium bromide / dichloromethane / 1 h / 20 °C / |Inert atmosphere 1.2: -78 - 20 °C / |Inert atmosphere 2.1: acetic acid; iron / ethanol / 0.08 h / 20 °C / |Reflux 3.1: potassium carbonate; 1,4-diaza-bicyclo[2.2.2]octane; copper(l) iodide / 1,4-dioxane / 5 h / |Schlenk technique; |Inert atmosphere; |Reflux View Scheme