potassium tert-butylate in tetrahydrofuran
T=0°C; 1 h;
参考文献
Al-Zaidi, Shakir M.R.; Crilley, Martine M. L.; Stoodley, Richard J.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1983 , p. 2259 - 2266
1: 23 percent / pyridine / 48 h / 0 °C
2: 53 percent / PCl5 / CH2Cl2 / 0.08 h
3: 59 percent / Et3N / CH2Cl2 / 12 h
4: 22 percent / potassium t-butoxide / tetrahydrofuran / 1 h / 0 °C
View Scheme
参考文献
Al-Zaidi, Shakir M.R.; Crilley, Martine M. L.; Stoodley, Richard J.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1983 , p. 2259 - 2266
1: 87 percent / HBr / acetic acid / 0.5 h
2: 52 percent / pyridine / 12 h
3: 53 percent / PCl5 / CH2Cl2 / 0.08 h
4: 59 percent / Et3N / CH2Cl2 / 12 h
5: 22 percent / potassium t-butoxide / tetrahydrofuran / 1 h / 0 °C
View Scheme
参考文献
Al-Zaidi, Shakir M.R.; Crilley, Martine M. L.; Stoodley, Richard J.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1983 , p. 2259 - 2266
1: DCC / CH2Cl2 / 1 h / 0 °C
2: 87 percent / HBr / acetic acid / 0.5 h
3: 52 percent / pyridine / 12 h
4: 53 percent / PCl5 / CH2Cl2 / 0.08 h
5: 59 percent / Et3N / CH2Cl2 / 12 h
6: 22 percent / potassium t-butoxide / tetrahydrofuran / 1 h / 0 °C
View Scheme
参考文献
Al-Zaidi, Shakir M.R.; Crilley, Martine M. L.; Stoodley, Richard J.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1983 , p. 2259 - 2266
1: 52 percent / pyridine / 12 h
2: 53 percent / PCl5 / CH2Cl2 / 0.08 h
3: 59 percent / Et3N / CH2Cl2 / 12 h
4: 22 percent / potassium t-butoxide / tetrahydrofuran / 1 h / 0 °C
View Scheme
参考文献
Al-Zaidi, Shakir M.R.; Crilley, Martine M. L.; Stoodley, Richard J.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1983 , p. 2259 - 2266
1: 59 percent / Et3N / CH2Cl2 / 12 h
2: 22 percent / potassium t-butoxide / tetrahydrofuran / 1 h / 0 °C
View Scheme
参考文献
Al-Zaidi, Shakir M.R.; Crilley, Martine M. L.; Stoodley, Richard J.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1983 , p. 2259 - 2266
1: 53 percent / PCl5 / CH2Cl2 / 0.08 h
2: 59 percent / Et3N / CH2Cl2 / 12 h
3: 22 percent / potassium t-butoxide / tetrahydrofuran / 1 h / 0 °C
View Scheme
参考文献
Al-Zaidi, Shakir M.R.; Crilley, Martine M. L.; Stoodley, Richard J.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1983 , p. 2259 - 2266
1: 43 percent / tetrahydrofuran / 24 h
2: 75 percent / pyridine / 12 h / Ambient temperature
3: 53 percent / PCl5 / CH2Cl2 / 0.08 h
4: 59 percent / Et3N / CH2Cl2 / 12 h
5: 22 percent / potassium t-butoxide / tetrahydrofuran / 1 h / 0 °C
View Scheme
参考文献
Al-Zaidi, Shakir M.R.; Crilley, Martine M. L.; Stoodley, Richard J.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1983 , p. 2259 - 2266
1: 53 percent / tetrahydrofuran / 3 h
2: 75 percent / pyridine / 12 h / Ambient temperature
3: 53 percent / PCl5 / CH2Cl2 / 0.08 h
4: 59 percent / Et3N / CH2Cl2 / 12 h
5: 22 percent / potassium t-butoxide / tetrahydrofuran / 1 h / 0 °C
View Scheme
参考文献
Al-Zaidi, Shakir M.R.; Crilley, Martine M. L.; Stoodley, Richard J.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1983 , p. 2259 - 2266
1: 84 percent Spectr. / 1M hydrochloric acid / acetone / 2 h
2: 59 percent / Et3N / CH2Cl2 / 12 h
3: 22 percent / potassium t-butoxide / tetrahydrofuran / 1 h / 0 °C
View Scheme
参考文献
Al-Zaidi, Shakir M.R.; Crilley, Martine M. L.; Stoodley, Richard J.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1983 , p. 2259 - 2266
