[3-(1-萘)苯基]-硼酸合成路线 （共 4 条）
反应条件
hydrogenchloride; n-butyllithium in tetrahydrofuran; hexane; toluene
参考文献
Idemitsu Kosan Co., Ltd.
Patent: US2009/8605 A1, 2009 ;
反应条件
1: 3-(1-naphthyl)-1-bromobenzene With n-butyllithium in tetrahydrofuran; hexane
T=-75°C; Inert atmosphere;
2: boric acid trimethyl ester in tetrahydrofuran; hexane
T=-75 - 20°C; Inert atmosphere;
3: With hydrogenchloride; water in tetrahydrofuran; hexane
T=20°C; 0.5 h;
参考文献
Mitsubishi Chemical Corporation
Patent: EP2471772 A1, 2012 ;
Location in patent: Page/Page column 57 ;
反应条件
1.1: sodium carbonate / tetrakis(triphenylphosphine) palladium(0) / toluene; ethanol; water / 6 h / Inert atmosphere; Reflux
2.1: n-butyllithium / hexane; tetrahydrofuran / -75 °C / Inert atmosphere
2.2: -75 - 20 °C / Inert atmosphere
2.3: 0.5 h / 20 °C
View Scheme
参考文献
Mitsubishi Chemical Corporation
Patent: EP2471772 A1, 2012 ;
反应条件
1.1: sodium carbonate / tetrakis(triphenylphosphine) palladium(0) / toluene; ethanol; water / 6 h / Inert atmosphere; Reflux
2.1: n-butyllithium / hexane; tetrahydrofuran / -75 °C / Inert atmosphere
2.2: -75 - 20 °C / Inert atmosphere
2.3: 0.5 h / 20 °C
View Scheme
参考文献
Mitsubishi Chemical Corporation
Patent: EP2471772 A1, 2012 ;
