1-苯基-1H-苯并三唑合成路线 （共 27 条）
反应条件
oxygen; palladium diacetate; caesium carbonate in N,N-dimethyl-formamide
T=110°C; Molecular sieve;
参考文献
Kumar, Rapolu Kiran; Ali, Md Ashif; Punniyamurthy, Tharmalingam
Organic Letters, 2011 , vol. 13, # 8 p. 2102 - 2105
反应条件
1: With copper(l) iodide in N,N-dimethyl-formamide
T=20°C; 0.25 h;
2: With caesium carbonate in N,N-dimethyl-formamide
T=20 - 55°C; 8 h;
参考文献
Kale, Raju R.; Prasad, Virendra; Hussain; Tiwari, Vinod K.
Tetrahedron Letters, 2010 , vol. 51, # 43 p. 5740 - 5743
反应条件
cesium fluoride in acetonitrile
T=20°C; 24 h;
参考文献
Liu, Zhijian; Larock, Richard C.
Journal of Organic Chemistry, 2006 , vol. 71, # 8 p. 3198 - 3209
反应条件
1,3-bis-(diphenylphosphino)propane; potassium acetate; palladium diacetate in N,N-dimethyl-formamide
T=110°C; 12 h; Inert atmosphereSealed tube; regioselective reaction;
参考文献
Zhou, Jun; He, Jianjun; Wang, Binjie; Yang, Weijun; Ren, Hongjun
Journal of the American Chemical Society, 2011 , vol. 133, # 18 p. 6868 - 6870
反应条件
potassium carbonate; L-proline; copper(l) chloride in dimethyl sulfoxide
T=160°C; 0.5 h; Microwave irradiation; regioselective reaction;
参考文献
Liu, Yuxiu; Yan, Wuming; Chen, Yunfeng; Petersen, Jeffrey L.; Shi, Xiaodong
Organic Letters, 2008 , vol. 10, # 23 p. 5389 - 5392
反应条件
1.1: hydrogenchloride / water / 0.08 h / 20 °C
1.2: 0 °C
1.3: 1.25 h / 0 °C
2.1: oxygen; palladium diacetate; caesium carbonate / N,N-dimethyl-formamide / 110 °C / Molecular sieve
View Scheme
参考文献
Kumar, Rapolu Kiran; Ali, Md Ashif; Punniyamurthy, Tharmalingam
Organic Letters, 2011 , vol. 13, # 8 p. 2102 - 2105
反应条件
N-hexadecyl-N,N,N-trimethylammonium bromide; potassium carbonate; [Pd(1,2-bis(diphenylphosphino)ethane)Cl2] in N,N-dimethyl-formamide
T=150°C; 8 h;
参考文献
Beletskaya, Irina P.; Davydov, Dmitri V.; Moreno-Manas, Marcial
Tetrahedron Letters, 1998 , vol. 39, # 31 p. 5617 - 5620
反应条件
3,4,5,6-tetramethyl-t-Bu-X-Phos; potassium phosphate; tris-(dibenzylideneacetone)dipalladium(0) in toluene
T=120°C; 5 h; Inert atmosphere;
参考文献
Ueda, Satoshi; Su, Mingjuan; Buchwald, Stephen L.
Angewandte Chemie - International Edition, 2011 , vol. 50, # 38 p. 8944 - 8947
反应条件
tert-Butyl thionitrate
T=160°C; 0.5 h;
参考文献
Oae, Shigeru; Iida, Kazuyuki; Shinhama, Koichi; Takata, Toshikazu
Bulletin of the Chemical Society of Japan, 1981 , vol. 54, # 8 p. 2374 - 2378
反应条件
potassium hydroxide; potassium tert-butylate in pyridine
T=20°C; 17 h;
参考文献
Brown, Richard A.; Fernando, Sharon I. S.; Roberts, Roger M. G.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1994 , # 2 p. 197 - 202
