in dichloromethane
byproducts: EtCHCMeCHO, cyclohex-2-enol; (N2); addn. of Sn-compd. to mixt. of 2.2 equiv. EtCHO and 1 equiv. BCl3 in CH2Cl2 at -78°C, warming to room temperature (1.5 h); treatment with sat. aq. NH4Cl;
参考文献
Marton, Daniele; Tagliavini, Giuseppe; Zordan, Michele; Wardell, James L.
Journal of Organometallic Chemistry, 1990 , vol. 390, # 2 p. 127 - 138
in dichloromethane
(N2); addn. of Sn-compd. to mixt. of 1 equiv. EtCHO and 1 equiv. BCl3 in CH2Cl2 at -78°C, warming to room temperature (1.5 h); further product; treatment with sat. aq. NH4Cl;
参考文献
Marton, Daniele; Tagliavini, Giuseppe; Zordan, Michele; Wardell, James L.
Journal of Organometallic Chemistry, 1990 , vol. 390, # 2 p. 127 - 138
boron trichloride in dichloromethane
T=-78 - 25°C; 1.5 h; other aldehydes and allylstannanes; comparison with BF3*OEt2 mediated reactions; Product distribution;
参考文献
Marton, Daniele; Tagliavini, Giuseppe; Zordan, Michele; Wardell, James L.
Journal of Organometallic Chemistry, 1990 , vol. 390, # 2 p. 127 - 138
