1: hydrogenchloride; water / methanol / 7 h / 20 °C 2: potassium acetate; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride / dimethyl sulfoxide / 40 h / 80 °C / |Inert atmosphere View Scheme

1: hydrogenchloride / water; methanol / 7 h / 20 °C 2: potassium acetate / (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride / dimethyl sulfoxide / 40 h / 80 °C / Inert atmosphere View Scheme

1: hydrogenchloride; water / methanol / 7 h / 20 °C 2: potassium acetate; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride / dimethyl sulfoxide / 40 h / 80 °C / |Inert atmosphere View Scheme

1: hydrogenchloride / water; methanol / 7 h / 20 °C 2: potassium acetate / (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride / dimethyl sulfoxide / 40 h / 80 °C / Inert atmosphere 3: sodium hydrogencarbonate / bis-triphenylphosphine-palladium(II) chloride / toluene; ethanol; water / 1 h / 120 °C / Inert atmosphere; Microwave irradiation View Scheme

hydrogenchloride in methanol; water T=20°C; 7 h;

1: With potassium acetate in chloroform T=0 - 20°C; 0.166667 h; 2: With 18-crown-6 ether; isopentyl nitrite 18 h;

1: 3-bromo-2-methyl-phenylamine; acetic anhydride With potassium acetate in chloroform T=0 - 20°C; 0.25 h; 2: isopentyl nitrite With 18-crown-6 ether in chloroform T=65°C; 18 h;

1: With potassium acetate in toluene T=60°C; 0.5 h; 2: With isopentyl nitrite in toluene T=60°C; 18 h;

1: in chloroform T=0 - 20°C; 0.166667 h; 2: With 18-crown-6 ether; isopentyl nitrite in chloroform 18 h; Heating / reflux; Product distribution / selectivity;

1: With potassium acetate; acetic anhydride in chloroform T=0 - 20°C; 0.166667 h; 2: With 18-crown-6 ether; isopentyl nitrite in chloroform 18 h; Heating / reflux; Product distribution / selectivity;