反,反-1,4-二苯基-1,3-丁二烯合成路线 (共 318 条)
反应条件
tetrakis(triphenylphosphine) palladium(0); water; silver(l) oxide in toluene T=80°C; Suzuki-Miyaura cross-coupling; 2 h; Inert atmosphere; optical yield given as percent dediastereoselective reaction;
参考文献
Bulletin of the Chemical Society of Japan, , vol. 82, # 10 p. 1292 - 1298
反应条件
1: E-cinnamyltriphenylphosphonium chloride in tetrahydrofuran; hexane T=-78°C; 1 h; Inert atmosphere; 2: N-(Phenylmethylene)methanesulphonamide in tetrahydrofuran; hexane T=-78 - 20°C; 12 h; Inert atmosphere; optical yield given as percent destereoselective reaction;
参考文献
Dong, De-Jun; Li, Hai-Hua; Tian, Shi-Kai
Journal of the American Chemical Society, 2010 , vol. 132, # 14 p. 5018 - 5020
反应条件
N,N’-di-tert-butylthiadiaziridine-1,1-dioxide; triphenylphosphine; copper(l) chloride T=65°C; 20 h; Inert atmosphere;
参考文献
Ramirez, Thomas A.; Zhao, Baoguo; Shi, Yian
Tetrahedron Letters, 2010 , vol. 51, # 14 p. 1822 - 1825
反应条件
lithium pentachloropalladate in acetonitrile T=25°C; 20 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Journal of Organometallic Chemistry, , vol. 423, # 1 p. C9 - C12
反应条件
2-propenylmagnesium bromide in tetrahydrofuran; diethyl ether T=0°C; 1 h;
参考文献
Synthesis, , # 3 p. 284 - 285
反应条件
lithium pentachloropalladate in acetonitrile T=25°C; 20 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Journal of Organometallic Chemistry, , vol. 423, # 1 p. C9 - C12
反应条件
lithium aluminium tetrahydride in tetrahydrofuran T=50°C; 1 h;
参考文献
Fleming, Ian; Kuehne, Hardy; Takai, Ken
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1986 , p. 725 - 728
反应条件
boron trifluoride diethyl etherate T=20°C; neat (no solvent); regioselective reaction;
参考文献
Narender; Papi Reddy; Madhur
Synthesis, 2009 , # 22 art. no. T09209SS, p. 3791 - 3796
反应条件
1: bromobenzene With n-butyllithium in tetrahydrofuran; hexane T=24°C; 0.00119444 h; 2: E-styryl bromide With palladium diacetate in tetrahydrofuran; hexane T=50°C; Murahashi coupling; 0.005 h;
参考文献
Chemistry - An Asian Journal, , vol. 7, # 5 p. 1061 - 1068
反应条件
palladium diacetate; sodium acetate in acetic acid T=50°C; 20 h;
参考文献
Cho, Chan Sik; Uemura, Sakae
Journal of Organometallic Chemistry, 1994 , vol. 465, # 1-2 p. 85 - 92