反,反-1,4-二苯基-1,3-丁二烯合成路线 (共 318 条)
反应条件
triethylamine; tetrakis(triphenylphosphine) palladium(0) in toluene T=85°C; Yield given;
参考文献
Journal of the American Chemical Society, , vol. 102, p. 2841
反应条件
tetrakis(triphenylphosphine) palladium(0); sodium carbonate in ethylene glycol dimethyl ether; water 0.166667 h; Ambient temperature;
参考文献
Kang, Suk-Ku; Lee, Hong-Woo; Jang, Su-Bum; Ho, Pil-Su
Journal of Organic Chemistry, 1996 , vol. 61, # 14 p. 4720 - 4724
反应条件
sodium hydroxide; tetrabutylammomium bromide; 4'-hydroxy-2'-chloropalladioacetophenone oxime dimer in water T=120°C; Hiyama coupling; P=3000.24 - 3750.3 Torr; 0.333333 h; microwave irradiation (40-45 W);
参考文献
Advanced Synthesis and Catalysis, , vol. 348, # 15 p. 2085 - 2091
反应条件
copper(l) chloride in dimethyl sulfoxide T=20°C; Dimerization; 6 h;
参考文献
Nishihara, Yasushi; Ikegashira, Kazutaka; Toriyama, Fumihiko; Mori, Atsunori; Hiyama, Tamejiro
Bulletin of the Chemical Society of Japan, 2000 , vol. 73, # 4 p. 985 - 990
反应条件
trimethylamine-N-oxide; tetrabutyl ammonium fluoride; palladium diacetate in tetrahydrofuran; 1,4-dioxane T=100°C; Heck-type reaction; 24 h;
参考文献
Inoue, Atsushi; Shinokubo, Hiroshi; Oshima, Koichiro
Journal of the American Chemical Society, 2003 , vol. 125, # 6 p. 1484 - 1485
反应条件
1: (E)-2-phenyl-1-[tris(trimethylsilyl)germyl]ethene With sodium hydroxide; dihydrogen peroxide in tetrahydrofuran; water T=20°C; 1 h; 2: chlorobenzene With tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran; water T=40°C; 12 h;
参考文献
Organic Letters, , vol. 6, # 12 p. 2047 - 2049
反应条件
1: phenylacetylene With Schwartz's reagent in toluene T=50°C; 1 h; 2: 4-nitro-benzoyl chloride With bis-triphenylphosphine-palladium(II) chloride in toluene T=20°C; 3 h; Further stages.;
参考文献
Organic and Biomolecular Chemistry, , vol. 5, # 2 p. 229 - 232
反应条件
1: With ethylmagnesium bromide; iron(II) chloride in diethyl ether T=20°C; 0.25 h; Inert atmosphere; 2: With hydrogenchloride; water in diethyl ether stereoselective reaction;
参考文献
Ilies, Laurean; Yoshida, Takumi; Nakamura, Eiichi
Journal of the American Chemical Society, 2012 , vol. 134, # 41 p. 16951 - 16954,4
反应条件
2,3-dichlorophenyl isocyanide; tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran Ambient temperature;
参考文献
Ito, Yoshihiko; Inouye, Masahiko; Murakami, Masahiro
Tetrahedron Letters, 1988 , vol. 29, # 42 p. 5379 - 5382
反应条件
copper(l) iodide; sodium carbonate in ethylene glycol dimethyl ether; water T=35°C; 0.666667 h;
参考文献
Kang, Suk-Ku; Yamaguchi, Tokutaro; Kim, Tae-Hyun; Ho, Pil-Su
Journal of Organic Chemistry, 1996 , vol. 61, # 26 p. 9082 - 9083