反,反-1,4-二苯基-1,3-丁二烯合成路线 (共 318 条)
反应条件
1: in tetrahydrofuran T=20°C; 0.5 h; Inert atmosphere; 2: With phosphonic acid diethyl ester in tetrahydrofuran T=20°C; Inert atmosphere; stereoselective reaction;
参考文献
Wang, Tongqiang; Hu, Yuanyuan; Zhang, Songlin
Organic and Biomolecular Chemistry, 2010 , vol. 8, # 10 p. 2312 - 2315
反应条件
tetrabutyl ammonium fluoride; palladium diacetate in tetrahydrofuran; acetonitrile 0.0833333 h; Ambient temperature;
参考文献
Kang, Suk-Ku; Kim, Tae-Hyun; Pyun, Sung-Jae
Journal of the Chemical Society - Perkin Transactions 1, 1997 , # 6 p. 797 - 798
反应条件
tetrabutyl ammonium fluoride; copper(l) iodide in tetrahydrofuran; acetonitrile 0.0833333 h; Ambient temperature;
参考文献
Kang, Suk-Ku; Kim, Tae-Hyun; Pyun, Sung-Jae
Journal of the Chemical Society - Perkin Transactions 1, 1997 , # 6 p. 797 - 798
反应条件
1: With hexacarbonyl molybdenum in diethyl ether T=-60°C; Addition; 2: With boron trifluoride diethyl etherate in diethyl ether T=-60 - 20°C; Dimerization; 3: With water in diethyl ether Hydrolysis; Further stages.;
参考文献
Barluenga, Jose; Rodriguez, Felix; Fananas, Francisco J.
Chemistry - A European Journal, 2000 , vol. 6, # 11 p. 1930 - 1937
反应条件
hydrogen; trimethylacetic anhydride; tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran T=80°C; P=22501.8 Torr; 24 h;
参考文献
Nagayama; Shimizu; Yamamoto
Bulletin of the Chemical Society of Japan, 2001 , vol. 74, # 10 p. 1803 - 1815
反应条件
indium; N-dodecane; lithium chloride; palladium on activated charcoal in N,N-dimethyl-formamide T=100°C; 12 h;
参考文献
Organic Letters, , vol. 7, # 2 p. 343 - 345
反应条件
1.1: bromotrimethylsilane / acetonitrile / 3 h / 20 °C 1.2: water / diethyl ether / 0.5 h / 20 °C 2.1: 66 percent Spectr. / Me3NO*2H2O; tetrabutylammonium fluoride / Pd(OAc)2 / tetrahydrofuran; dioxane / 24 h / 100 °C View Scheme
参考文献
Journal of the American Chemical Society, , vol. 125, # 6 p. 1484 - 1485
反应条件
2: Et3N / (Ph3P)4Pd / toluene / 85 °C View Scheme
参考文献
Journal of the American Chemical Society, , vol. 102, p. 2841
反应条件
2: Et3N / (Ph3P)4Pd / toluene / 85 °C View Scheme
参考文献
Journal of the American Chemical Society, , vol. 102, p. 2841
反应条件
1: With copper(l) iodide in acetonitrile T=20°C; 0.166667 h; Inert atmosphere; 2: With cesium fluoride in acetonitrile 2 h; Inert atmosphereReflux;
参考文献
Blackwell, David T.; Galloway, Warren R. J. D.; Spring, David R.
Synlett, 2011 , # 15 art. no. D10711ST, p. 2140 - 2144