反,反-1,4-二苯基-1,3-丁二烯合成路线 （共 318 条）
反应条件
palladium diacetate; [14C]-Orotic acid; cesium fluoride in 1,4-dioxane T=100°C; Stille Cross Coupling; 18 h; Sealed tubeInert atmosphereSchlenk technique;
参考文献
Zhang, Hong-Ping; Li, Xiao-Fang; Li, Hong-Yan
Journal of Chemical Research, 2013 , vol. 37, # 4 p. 219 - 222
反应条件
cesium fluoride in tetrahydrofuran Heating;
参考文献
Kawashima, Takayuki; Ishii, Takafumi; Inamoto, Naoki
Bulletin of the Chemical Society of Japan, 1987 , vol. 60, p. 1831 - 1838
反应条件
tetrakis(triphenylphosphine) palladium(0) in methanol T=25°C; P=760 Torr; 20 h;
参考文献
Journal of Organometallic Chemistry, , vol. 344, p. C5 - C7
反应条件
sodium acetate; acetone; copper dichloride T=10°C;
参考文献
Journal of Organic Chemistry, , vol. 9, p. 415,417
Journal of the American Chemical Society, , vol. 66, p. 412,414
反应条件
1: 99 percent / tri(2-furyl)phosphine; Et3N / Pd2(dba)3*CHCl3 / tetrahydrofuran / 24 h / 50 °C 2: 99 percent / CuI; CsF / acetonitrile / 3 h / 20 °C View Scheme
参考文献
Organic Letters, , vol. 6, # 21 p. 3695 - 3698
反应条件
sodium hydroxide; 4-hydroacetophenone oxime-derived palladacycle in water T=120°C; Hiyama reaction; 0.333333 h; microwave irradiation;
参考文献
Journal of Organic Chemistry, , vol. 73, # 6 p. 2315 - 2322
反应条件
carbon monoxide; tetrakis(triphenylphosphine) palladium(0) in methanol treatment with CO (1 atm) in methanol (25 ° C, 20 h, catalyst: Pd(PPh3)4); GLC;
参考文献
Journal of Organometallic Chemistry, , vol. 344, p. C5 - C7
反应条件
Pd0(tris(tert-butyl)phosphine)2; water; potassium carbonate in toluene T=20°C; Suzuki-Miyaura cross-coupling; 24 h; Inert atmosphere; optical yield given as percent dediastereoselective reaction;
参考文献
Wakioka, Masayuki; Mutoh, Yuichiro; Takita, Ryo; Ozawa, Fumiyuki
Bulletin of the Chemical Society of Japan, 2009 , vol. 82, # 10 p. 1292 - 1298
反应条件
1: With 1,3-bis(2,4,6-trimethylphenyl)imidazolinium chloride; Ni(acac)2 in tetrahydrofuran; toluene T=80°C; Wenkert synthesis; 36 h; Inert atmosphere; 2: With iodine in hexane T=20°C; Inert atmosphereIrradiation;
参考文献
Hintermann, Lukas; Schmitz, Marco; Chen, Yun
Advanced Synthesis and Catalysis, 2010 , vol. 352, # 14-15 p. 2411 - 2415
反应条件
1: With 1,3-bis(2,4,6-trimethylphenyl)imidazolinium chloride; Ni(acac)2 in tetrahydrofuran; toluene T=80°C; Wenkert synthesis; 36 h; Inert atmosphereIrradiation; 2: With iodine in hexane T=20°C; Inert atmosphere;
参考文献
Hintermann, Lukas; Schmitz, Marco; Chen, Yun
Advanced Synthesis and Catalysis, 2010 , vol. 352, # 14-15 p. 2411 - 2415
