3,3-二甲基-1-(三氟甲基)-1,2-苯并碘氧杂戊环合成路线 （共 71 条）
反应条件
copper(I) isothiocyanate in acetonitrile
T=20°C; 16 h;
参考文献
Zheng, Huidong; Huang, Yuanyuan; Wang, Zhiwei; Li, Huaifeng; Huang, Kuo-Wei; Yuan, Yaofeng; Weng, Zhiqiang
Tetrahedron Letters, 2012 , vol. 53, # 49 p. 6646 - 6649
反应条件
1: N1,N3-Dimethyluracil With 2,6-di-tert-butyl-pyridine; bis(η4-1,5-cyclooctadiene)-di-μ-methoxy-diiridium(I); 4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl-4',4',5',5'-tetramethyl-1,3,2-dioxaborolane in tetrahydrofuran
T=80°C; 24 h; Sealed tubeInert atmosphere;
2: Togni’s reagent With 1,10-phenanthroline; copper(I) thiophene-2-carboxylate; lithium hydroxide hydrate in tetrahydrofuran; dichloromethane
T=50°C; 22 h; Reflux;
参考文献
Cernova, Miroslava; Pohl, Radek; Klepetarova, Blanka; Hocek, Michal
Heterocycles, 2014 , vol. 89, # 5 p. 1159 - 1171
反应条件
tetra-(n-butyl)ammonium iodide; potassium carbonate in acetonitrile
T=20°C; 28 h;
参考文献
Eisenberger, Patrick; Gischig, Sebastian; Togni, Antonio
Chemistry - A European Journal, 2006 , vol. 12, # 9 p. 2579 - 2586
反应条件
1,10-phenanthroline; tetrabutyl ammonium fluoride; cupric trifluoroacetate in dimethyl sulfoxide
T=130°C; 8 h; Inert atmosphereSealed tube;
参考文献
Lin, Xiaoxi; Wang, Guimei; Li, Huaifeng; Huang, Yuanyuan; He, Weiming; Ye, Dandan; Huang, Kuo-Wei; Yuan, Yaofeng; Weng, Zhiqiang
Tetrahedron, 2013 , vol. 69, # 12 p. 2628 - 2632
反应条件
tris(trimethylsilyl)silyl chloride in acetonitrile
T=80°C; 24 h; Inert atmosphere;
参考文献
Wiehn, Matthias S.; Vinogradova, Ekaterina V.; Togni, Antonio
Journal of Fluorine Chemistry, 2010 , vol. 131, # 9 p. 951 - 957
反应条件
[2,2']bipyridinyl; cupric trifluoroacetate; silver(l) oxide in acetonitrile
T=20°C; 12 h; Schlenk techniqueInert atmosphereMolecular sieve;
参考文献
Huang, Yuanyuan; Fang, Xin; Lin, Xiaoxi; He, Weiming; Yuan, Yaofeng; Weng, Zhiqiang; Li, Huaifeng; Huang, Kuo-Wei
Tetrahedron, 2012 , vol. 68, # 48 p. 9949 - 9953,5
反应条件
copper(l) iodide; 1,10-phenanthroline; potassium carbonate in diethylene glycol dimethyl ether
T=35°C; 14 h; Inert atmosphere;
参考文献
Liu, Tianfei; Shen, Qilong
Organic Letters, 2011 , vol. 13, # 9 p. 2342 - 2345
反应条件
[2,2']bipyridinyl; cupric trifluoroacetate in acetonitrile
T=20°C; 12 h; Schlenk techniqueInert atmosphereMolecular sieve;
参考文献
Huang, Yuanyuan; Fang, Xin; Lin, Xiaoxi; He, Weiming; Yuan, Yaofeng; Weng, Zhiqiang; Li, Huaifeng; Huang, Kuo-Wei
Tetrahedron, 2012 , vol. 68, # 48 p. 9949 - 9953,5
反应条件
[2,2']bipyridinyl; cupric trifluoroacetate in acetonitrile
T=20°C; 12 h; Schlenk techniqueInert atmosphereMolecular sieve; Reagent/catalystSolvent;
参考文献
Huang, Yuanyuan; Fang, Xin; Lin, Xiaoxi; He, Weiming; Yuan, Yaofeng; Weng, Zhiqiang; Li, Huaifeng; Huang, Kuo-Wei
Tetrahedron, 2012 , vol. 68, # 48 p. 9949 - 9953,5
反应条件
copper(l) iodide; 1,10-phenanthroline; potassium carbonate in diethylene glycol dimethyl ether
T=35°C; 14 h; Inert atmosphere;
参考文献
Liu, Tianfei; Shen, Qilong
Organic Letters, 2011 , vol. 13, # 9 p. 2342 - 2345
