(5-羟基-1-环戊烯)-苯甲酮合成路线 （共 11 条）
反应条件
(CF3(CF2)7CH2CH2CH2)3P in acetonitrile
T=60 - 64°C; Morita-Baylis-Hillman reaction; 24 h; Inert atmosphere;
参考文献
Seidel, Florian O.; Gladysz, John A.
Advanced Synthesis and Catalysis, 2008 , vol. 350, # 14-15 p. 2443 - 2449
反应条件
(η5-C5H5)Re(NO)(PPh3)(CH2PPh2) in benzene
T=20°C; Morita-Baylis-Hillman reaction; 1.5 h;
参考文献
Seidel, Florian; Gladysz, John A.
Synlett, 2007 , # 6 p. 986 - 988
反应条件
poly[styrene-co-(4-hydroxystyrene)-co-(4-styryl-PPh2)] in 1,2-dichloro-ethane
T=20°C; Morita-Baylis-Hillman reaction; 18 h;
参考文献
Kwong, Cathy Kar-Wing; Huang, Rui; Zhang, Minjuan; Shi, Min; Toy, Patrick H.
Chemistry - A European Journal, 2007 , vol. 13, # 8 p. 2369 - 2376
反应条件
N-benzyl-N,N,N-triethylammonium chloride; titanium tetrachloride in dichloromethane
T=0°C; Michael addition/aldol cyclization;
参考文献
Yagi, Kazunari; Turitani, Takayuki; Shinokubo, Hiroshi; Oshima, Koichiro
Organic Letters, 2002 , vol. 4, # 18 p. 3111 - 3114
反应条件
1: 50 percent / toluene / 4 h / Heating
2: tetrahydrofuran / 0 - 20 °C
3: Pb(OAc)4 / acetonitrile / 20 °C
4: 10 percent / PPh3 / 1,2-dichloro-ethane / 48 h / 20 °C
View Scheme
参考文献
Teng, Wen-Dong; Huang, Rui; Kwong, Cathy Kar-Wing; Shi, Min; Toy, Patrick H.
Journal of Organic Chemistry, 2006 , vol. 71, # 1 p. 368 - 371
反应条件
1: tetrahydrofuran / 0 - 20 °C
2: Pb(OAc)4 / acetonitrile / 20 °C
3: 10 percent / PPh3 / 1,2-dichloro-ethane / 48 h / 20 °C
View Scheme
参考文献
Teng, Wen-Dong; Huang, Rui; Kwong, Cathy Kar-Wing; Shi, Min; Toy, Patrick H.
Journal of Organic Chemistry, 2006 , vol. 71, # 1 p. 368 - 371
反应条件
1: Pb(OAc)4 / acetonitrile / 20 °C
2: 10 percent / PPh3 / 1,2-dichloro-ethane / 48 h / 20 °C
View Scheme
参考文献
Teng, Wen-Dong; Huang, Rui; Kwong, Cathy Kar-Wing; Shi, Min; Toy, Patrick H.
Journal of Organic Chemistry, 2006 , vol. 71, # 1 p. 368 - 371
反应条件
oxygen in acetonitrile
Heating;
参考文献
Little, R. Daniel; Losinski-Dang, Lorraine; Venegas, Manuel G.; Merlic, Craig
Tetrahedron Letters, 1983 , vol. 24, # 42 p. 4499 - 4502
反应条件
1: 48 percent / CH2Cl2 / 48 h / 0 °C
2: 50 percent / piperidine / CDCl3 / 168 h / 20 °C
View Scheme
参考文献
Richards, Elinor L; Murphy, Patrick J; Dinon, Francesca; Fratucello, Silvia; Brown, Paul M; Gelbrich, Thomas; Hursthouse, Michael B
Tetrahedron, 2001 , vol. 57, # 36 p. 7771 - 7784
反应条件
1: 91 percent / (η5-C5H5)Re(NO)(PPh3)(CH2PPh2) / benzene / 1.5 h / 20 °C
View Scheme
参考文献
Seidel, Florian; Gladysz, John A.
Synlett, 2007 , # 6 p. 986 - 988
