(2E)-1-(2-羟基苯基)-3-苯基-2-丙烯-1-酮合成路线 （共 83 条）
反应条件
Rhodococcus sp. DSM 364 in acetone
T=28°C; 168 h; Microbiological reaction;
参考文献
Stompor, Monika; Potaniec, Bartomiej; Szumny, Antoni; Zielinski, Pawe; Zonierczyk, Anna Katarzyna; Aniol, Miroslaw
Journal of Molecular Catalysis B: Enzymatic, 2013 , vol. 97, p. 283 - 288
反应条件
sodium hydroxide in ethanol
52 h; Heating;
参考文献
Chawla, H. Mohindra; Sharma, S. Kumar
Heterocycles, 1987 , vol. 26, # 6 p. 1527 - 1534
反应条件
lanthanum in tetrahydrofuran
2 h; Heating;
参考文献
Li, Wei-Dong Z.; Ma, Bao-Chun
Organic Letters, 2005 , vol. 7, # 2 p. 271 - 274
反应条件
Adogen-464; potassium carbonate in benzene
24 h; Ambient temperature;
参考文献
Patonay, Tamas; Patonay-Peli, Erzsebet; Litkei, Gyoergy
Tetrahedron, 1987 , vol. 43, # 8 p. 1827 - 1834
反应条件
1: 54 percent / N-chlorosuccinimide, pyridine / CHCl3 / 2 h / Heating
2: 38 percent / H2, boric acid / Raney-Ni / methanol; H2O
3: p-TsOH / CHCl3 / 0.5 h / Heating
View Scheme
参考文献
Thomsen, Ib; Torssell, Kurt B. G.
Acta Chemica Scandinavica, Series B: Organic Chemistry and Biochemistry, 1988 , vol. 42, # 5 p. 303 - 308
反应条件
1: 38 percent / H2, boric acid / Raney-Ni / methanol; H2O
2: p-TsOH / CHCl3 / 0.5 h / Heating
View Scheme
参考文献
Thomsen, Ib; Torssell, Kurt B. G.
Acta Chemica Scandinavica, Series B: Organic Chemistry and Biochemistry, 1988 , vol. 42, # 5 p. 303 - 308
反应条件
1: 54 percent / N-chlorosuccinimide, pyridine / CHCl3 / 2 h / Heating
2: 38 percent / H2, boric acid / Raney-Ni / methanol; H2O
3: p-TsOH / CHCl3 / 0.5 h / Heating
View Scheme
参考文献
Thomsen, Ib; Torssell, Kurt B. G.
Acta Chemica Scandinavica, Series B: Organic Chemistry and Biochemistry, 1988 , vol. 42, # 5 p. 303 - 308
反应条件
1,1'-bis-(diphenylphosphino)ferrocene; [RhCl(η2:η2-cycloocta-1,5-diene)]2; sodium carbonate in benzene
4 h; Heating; Yield given. Yields of byproduct given;
参考文献
Kokubo, Ken; Matsumasa, Kenji; Miura, Masahiro; Nomura, Masakatsu
Journal of Organic Chemistry, 1997 , vol. 62, # 14 p. 4564 - 4565
反应条件
C5H2Ph4; [{(η5-C5Me5)RhCl}2(μ-Cl)2]; copper diacetate in 1,2-dichloro-ethane
T=120°C; Mizoroki-Heck reaction; 1 h; Inert atmosphere; regioselective reaction;
参考文献
Shi, Zhuangzhi; Schroeder, Nils; Glorius, Frank
Angewandte Chemie - International Edition, 2012 , vol. 51, # 32 p. 8092 - 8096
反应条件
N,N,N-trimethyl-2-hydroxyethyl-ammonium hydroxide
T=60°C; Title compound not separated from byproducts;
参考文献
Abello, Sonia; Medina, Francisco; Rodriguez, Xavier; Cesteros, Yolanda; Salagre, Pilar; Sueiras, Jesus E.; Tichit, Didier; Coq, Bernard
Chemical Communications, 2004 , # 9 p. 1096 - 1097
