N,N-二异丙基乙胺硼烷络合物合成路线 (共 3 条)
反应条件
1: With lithium hydride in tetrahydrofuran T=20°C; Inert atmosphere; 2: With AlCl3, aluminium chloride in tetrahydrofuran T=0 - 20°C; Inert atmosphere;
参考文献
Veeraraghavan Ramachandran; Raju, Bhimapaka C.; Gagare, Pravin D.
Organic Letters, 2012 , vol. 14, # 24 p. 6119 - 6121
反应条件
bis-(trifluoromethylsulphonyl)amine in dichloromethane-d2 T=20°C; Inert atmosphere;
参考文献
Organometallics, , vol. 32, # 22 p. 6701 - 6711
反应条件
di-tert-butyl peroxide in further solvent(s)
Kinetics; byproducts: t-butanol; Irradiation (UV/VIS); flash photolysis with light pulses (50 Hz, 308 nm, 10 ns duration, XeClexcimer laser) in cyclopropane-t-pentyl alcohol soln. (3:1) at 224 K, or in cyclopropane-t-pentyl alcohol-t-BuOH soln. (6:2:1), or in cyclopropane-oxirane soln. (3:1); detected by ESR spectroscopy;;
参考文献
Baban, Jehan A.; Goddard, Jeffrey P.; Roberts, Brian P.
Journal of Chemical Research, Synopses, 1986 , p. 30 - 31